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Assertion (A) : Hydrolysis of (-)-2-brom...

Assertion (A) : Hydrolysis of `(-)-2`-bromooctane proceeds with inversion of configuration.
Reason (R ) : This reaction proceeds through the formation of a carbocation.

A

Assertion and reason both are correct and reason is correct explanation of assertion.

B

Assertion and reason both are wrong statements.

C

Assertion is correct but reason is wrong statement.

D

Assertion is wrong but reason is correct statement.

Text Solution

Verified by Experts

The correct Answer is:
C
`S_(N)2` reaction passes through pentavalent transition staste of a carbon.
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Nucleophilic aliphatic substitution reaction is mainly of two types: S_(N)1 and S_(N)2 . The S_(N)1 mechanism is a two step process. Reaction velocity of S_(N)1 reaction depends only on the concentration of the substrate. Since product formation takes place by the formation of carbocation, optically active substrate gives (+) and (-) forms of the product. In most of the cases the product usually consists of 5-20% inverted product and 80-95% racemised species. The more stable the carbocation, the greater is the proportion of racemisation. In solvolysis reaction, the more nucleophilic the solvent, the greater is the proportion of inversion. Which one of the following compound will give S_(N)1 reaction predominantly?

Nucleophilic aliphatic substitution reaction is mainly of two types: S_(N)1 and S_(N)2 . The S_(N)1 mechanism is a two step process. Reaction velocity of S_(N)1 reaction depends only on the concentration of the substrate. Since product formation takes place by the formation of carbocation, optically active substrate gives (+) and (-) forms of the product. In most of the cases the product usually consits of 5-20% inverted product and 80-95% racemised species. The more stable the carbocation, the greater is the proportion of racemisation. In solvolysis reaction, the more nucleophilic the solvent, the greater is the proportion of inversion. For the gives reaction, Which substrate will give maximum racemisation?