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In the following reaction, the major pro...

In the following reaction, the major product formed will be ……
`CH_(3)-overset(CH_(3))overset("| ")underset("Cl ")underset("| ")("C ")-CH=CH_(2)+KSH overset(DMSO)rarr (P)`

A

`CH_(3)-overset(CH_(3))overset("| ")underset("SH ")underset("| ")("C ")-CH=CH_(2)`

B

`CH_(3)-overset(CH_(2))overset("|| ")("C ")-CH=CH_(2)`

C

`CH_(3)-overset(CH_(3))overset("| ")("C ")=CH-CH_(2)-SH`

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
C
The allylic carbon is sterically hindered and thus the reaction takes place by the rearrangment of the double bond.
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Write IUPAC name of the following (b) CH_(3)-overset(CH_(3))overset("| ")underset(OH)underset("| ")"C "-CH_(3)

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Knowledge Check

  • H_(3)C-underset(CH_(3))underset("| ")("C ")H-CH=CH_(2)overset(HBr)rarr

    A
    `CH_(3)-underset(CH_(3))underset("| ")("C ")H-underset("Br ")underset("| ")("C ")H-CH_(3)`
    B
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    C
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    D
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  • Which monomer is present in [-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(2)-]_(n) polymer ?

    A
    Propylene
    B
    Propane
    C
    2-methyl propene
    D
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  • In the following reactions, the final product B is ….. CH_(3)Cl overset(KCN)rarr A overset(H^(+)//H_(2)O)rarr B

    A
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    B
    H COOH
    C
    `CH_(3)NH_(2)`
    D
    `CH_(3)COCH_(3)`

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