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In the following reaction, the major pro...

In the following reaction, the major product formed will be ……
`CH_(3)-overset(CH_(3))overset("| ")underset("Cl ")underset("| ")("C ")-CH=CH_(2)+KSH overset(DMSO)rarr (P)`

A

`CH_(3)-overset(CH_(3))overset("| ")underset("SH ")underset("| ")("C ")-CH=CH_(2)`

B

`CH_(3)-overset(CH_(2))overset("|| ")("C ")-CH=CH_(2)`

C

`CH_(3)-overset(CH_(3))overset("| ")("C ")=CH-CH_(2)-SH`

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
C

The allylic carbon is sterically hindered and thus the reaction takes place by the rearrangment of the double bond.
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KUMAR PRAKASHAN-HALOALKANES AND HALOARENES-SECTION - E Multiple Choice Questions
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  2. The final product in the reaction is :

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  3. In the following reaction, the major product formed will be …… CH(3...

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  4. Which of the following is true for the given reaction ?

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  5. The major product in the given reaction will be ….. CH(3)-overset("...

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  6. The major product of the reaction is …….

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  7. The major product in the given reaction is ….. CH(3)-CH(2)-underset...

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  8. The stereochemical relation between two compounds (A) and (B) is ……

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  9. In the following reaction : X is …….

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  10. An aromatic compound C(7)H(6)Cl(2) (A) gives AgCl on boiling with alco...

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  11. Which of the following is most reactive by S(N)I ? (tBu = tert-Butyl ...

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  12. What is mixture of dextro and levo isomers called ?

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  13. The reaction that take place is aryl halide is ……

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  14. 2CH(3)CH(2)Cl+2Na overset(" Dry ")underset(" Ether ")rarr Z+2NaCl. ...

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  15. Chlorination of carbon disulphide gives ………

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  16. In the given reaction, the product (Z) is ……. underset("Ethanol")(C...

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  17. Iodoform is used as ……..

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  18. To prevent oxidation of chloroform …….. is added.

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  19. The product (Z) is ……..

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  20. C Cl(4)+H(2)overset(Fe)underset(H(2)O)rarr (A)+HCl The product (A)...

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