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An aromatic compound C(7)H(6)Cl(2) (A) g...

An aromatic compound `C_(7)H_(6)Cl_(2)` (A) gives AgCl on boiling with alcoholic `AgNO_(3)` solution and yeilds `C_(7)H_(7)Ocl` on treatement with sodium hydroxide (A) on oxidation gives monochlorobenzoic acid. The compound (A).

A

B

C

D

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An organic compound A has molecular formula C_(10)H_(17)Br and it is non-resolvable. A does not decolourise brown colour of bromine water solution. A on treatement with (CH_(3))_(2 COK//(CH_(3))_(3)COH yields B as major product. B on treatment with H_(2)//Pt yields (C_(10)H_(16)) which on treatment with CI_(2)//hv yields three monochloro derivative. Also B on boiling with acidic permanganate solution yields C(C_(10)H_(16)O_(3))C . on heating with sodalime yields D(C_(9)H_(16)O).D on reducing with LiAIH_(4) followed by heating product with concentrated H_(2)SO_(4) yields E(C_(9)H_(16)) as major product. E on treatment with ozone followed by work-up with Zn-H_(2)O yields 6-Keto nonanal. Compound A is:

An organic compound A has molecular formula C_(10)H_(17)Br and it is non-resolvable. A does not decolourise brown colour of bromine water solution. A on treatement with (CH_(3))_(2 COK//(CH_(3))_(3)COH yields B as majot product. B on treatment with H_(2)//Pt yields (C_(10)H_(16)) which on treatment with CI_(2)//hv yields three monochloro derivative. Also B on boiling with acidic permanganate solution yields C(C_(10)H_(16)O_(3))C . on heating with sodalime yields D(C_(9)H_(16)O).D on reducing with LiAIH_(4) followed by heating product with concentrated H_(2)SO_(4) yields E(C_(9)H_(16)) as major product. E on treatment with ozone followed by work-up with Zn-H_(2)O yields 6-Ketononanal. Compound B is:

An organic compound A has molecular formula C_(10)H_(17)Br and it is non-resolvable. A does not decolourise brown colour of bromine water solution. A on treatement with (CH_(3))_(2 COK//(CH_(3))_(3)COH yields B as majot product. B on treatment with H_(2)//Pt yields (C_(10)H_(16)) which on treatment with CI_(2)//hv yields three monochloro derivative. Also B on boiling with acidic permanganate solution yields C(C_(10)H_(16)O_(3))C . on heating with sodalime yields D(C_(9)H_(16)O).D on reducing with LiAIH_(4) followed by heating product with concentrated H_(2)SO_(4) yields E(C_(9)H_(16)) as major product. E on treatment with ozone followed by work-up with Zn-H_(2)O yields 6-Ketononanal. Compound D is:

KUMAR PRAKASHAN-HALOALKANES AND HALOARENES-SECTION - E Multiple Choice Questions
  1. The stereochemical relation between two compounds (A) and (B) is ……

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  2. In the following reaction : X is …….

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  3. An aromatic compound C(7)H(6)Cl(2) (A) gives AgCl on boiling with alco...

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  4. Which of the following is most reactive by S(N)I ? (tBu = tert-Butyl ...

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  5. What is mixture of dextro and levo isomers called ?

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  6. The reaction that take place is aryl halide is ……

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  7. 2CH(3)CH(2)Cl+2Na overset(" Dry ")underset(" Ether ")rarr Z+2NaCl. ...

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  8. Chlorination of carbon disulphide gives ………

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  9. In the given reaction, the product (Z) is ……. underset("Ethanol")(C...

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  10. Iodoform is used as ……..

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  11. To prevent oxidation of chloroform …….. is added.

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  12. The product (Z) is ……..

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  13. C Cl(4)+H(2)overset(Fe)underset(H(2)O)rarr (A)+HCl The product (A)...

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  14. When chloroform is kept open in air, a poisonous gas phosgene is forme...

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  15. Which polyhalogen compound is used as a fire extinguisher in case of f...

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  16. Which product is obtained when chlorobenzene react with 6 to 8% aq. Na...

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  17. What is 'X' in given reaction ?

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  18. Which product is obtained when chlorobenzene react with NaCN in presen...

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  19. What is Z given reaction ?

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  20. Which factor is important to determine stability of carbocation ?

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