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In an S(N)1 reaction on chiral centres, ...

In an `S_(N)1` reaction on chiral centres, there is :

A

100 % retention

B

100 % inversion

C

100 % racemization

D

inversion more than retention leading to partial racemization.

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Verified by Experts

The correct Answer is:
D

`S_(N)1` reaction gives racemic mixture with slight predominance of that isomer which corresponds to inversion because `S_(N)1` also depends upon the degree of shielding of the front side of the reacting carbon.
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KUMAR PRAKASHAN-HALOALKANES AND HALOARENES-SECTION - E Multiple Choice Questions
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  3. In an S(N)1 reaction on chiral centres, there is :

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  4. Which of the following biphenyls is optically active ?

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  5. The absolute configuration of

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  6. H(3)C-underset(CH(3))underset("| ")("C ")H-CH=CH(2)overset(HBr)rarr

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  7. Which of the following upon treatment with tert-BuONa followed by addi...

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  8. The major product obtained in the following reaction is …….

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  9. Which of the following pairs shows highest bond dissociation enthalpy ...

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  10. Among halogens, the one which can oxidise water to oxygen is ……

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  11. The letter 'D' in D-glucose signifies.

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  12. Which of the compounds will react faster in S(N)1 reaction with the ""...

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  13. Identify the major products P, Q and R in the following sequence of re...

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  14. Which of the following carbocations is expected to be most stable ?

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  15. Which is the final product obtained by the reaction of a grignard reag...

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  16. Compound A, C(8)H(10)O is found to react with NaOI (produced by reacti...

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