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S(N)1 reaction undergoes in which type o...

`S_(N)1` reaction undergoes in which type of fission ?

A

Homolytic fission

B

Heterolytic fission

C

Heterolytic fusion

D

Nuclear fission

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The correct Answer is:
B

Heterolytic fission C - Br bond of `3^(@)` - halide occurs in all `S_(N)1` reaction
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Nucleophilic aliphatic substitution reaction is mainly of two types: S_(N)1 and S_(N)2 . The S_(N)1 mechanism is a two step process. Reaction velocity of S_(N)1 reaction depends only on the concentration of the substrate. Since product formation takes place by the formation of carbocation, optically active substrate gives (+) and (-) forms of the product. In most of the cases the product usually consists of 5-20% inverted product and 80-95% racemised species. The more stable the carbocation, the greater is the proportion of racemisation. In solvolysis reaction, the more nucleophilic the solvent, the greater is the proportion of inversion. Which one of the following compound will give S_(N)1 reaction predominantly?

Nucleophilic aliphatic substitution reaction is mainly of two types: S_(N)1 and S_(N)2 . The S_(N)1 mechanism is a two step process. Reaction velocity of S_(N)1 reaction depends only on the concentration of the substrate. Since product formation takes place by the formation of carbocation, optically active substrate gives (+) and (-) forms of the product. In most of the cases the product usually consits of 5-20% inverted product and 80-95% racemised species. The more stable the carbocation, the greater is the proportion of racemisation. In solvolysis reaction, the more nucleophilic the solvent, the greater is the proportion of inversion. For the gives reaction, Which substrate will give maximum racemisation?

The formation of Cyanohydrin from Acetone is which type of reaction ?

What is fission? Explain different types of fission.

KUMAR PRAKASHAN-HALOALKANES AND HALOARENES-SECTION - E Multiple Choice Questions
  1. Which reaction is used to prepare Toluene from chlorobenzene ?

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  2. What is the formula of ''Pyrene'' ?

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  3. Which reagent is used to prepare fluoromethane by Swartz reaction.

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  4. S(N)1 reaction undergoes in which type of fission ?

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  5. What is A & B ?

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  6. Which is the correct order of boiling point of halomethane ?

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  7. What is A and B ?

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  8. How many Carbon, Hydrogen and Chlorine atoms are present in DDT ?

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  9. Match the proper pairs : {:(,[A],,[B]),((P),S(N)2,(i),"Freon"),((Q)...

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  10. Which of the following substance is used to extinguish fire in substan...

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  11. How many sigma - and pi - bonds are present in the structure of D.D.T....

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  12. Which compound will give unimolecular nucleophilic substitution reacti...

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  13. Which of the following compound is optically inactive ?

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  14. Which compound is optically active ?

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  15. Which of the following substance does not produce Triodomethane with t...

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  16. Which substance is added in chloroform before the use of it as anesthe...

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  17. Which of the following compound has highest reactivity towards S(N)1 r...

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  18. Which of the following has the highest dipole moment ?

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  19. The position of -Br in the compound in CH(3)CH=CHC(Br)(CH(3))(2) can b...

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  20. The IUPAC name of the major organic product of the reaction : CH(3)C...

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