Home
Class 11
CHEMISTRY
Tl(OH)3 is less basic than TlOH. Why ?...

`Tl(OH)_3` is less basic than `TlOH`. Why ?

Text Solution

Verified by Experts

`Tl(OH)` is less basic than TIOH. The polarising power of `Tl^(3+)` is more than `Tl^(1+)` .
Tl-O bond is TI`(OH)_3` becomes stronger than that in TlOH. As `Tl-O` bond becomes stronger, release of `OH^-` ion becomes less possible. Hence, basic nature of `Tl(OH)_3` is less. Basic strength of `TlOH ~~ NaOH`.
Promotional Banner

Topper's Solved these Questions

  • ELEMENTS OF BORON FAMILY

    AAKASH SERIES|Exercise SUBJECTIVE EXERCISE-1 (Long answer questions)|7 Videos

  • ELEMENTS OF BORON FAMILY

    AAKASH SERIES|Exercise SUBJECTIVE EXERCISE-1 (Short answer questions)|14 Videos

  • ELECTRONIC EFFECTS AND REACTION INTERMEDIATES

    AAKASH SERIES|Exercise ADDITIONAL PRACTICE EXERCISE (LEVEL - II (PRACTICE SHEET ADVANCE)) (Integer Type Questions)|3 Videos

  • ELEMENTS OF CARBON FAMILY

    AAKASH SERIES|Exercise OBJECTIVE EXERCISE - 3 (Recent AIPMT/NEET Questions) |10 Videos

Similar Questions

Explore conceptually related problems

Aniline is less basic than

H_(2)S is less acidic than H_(2)Te . Why ?

Aniline is less basic than ammonia. Why?

Phenol is more acidic and ethanol is less acidic than water. Why ?

CH_3 COOH is less acidic than HCOOH. It is due to which effect

Basic nature of Lu(OH)_(2) is less than that of La(OH)_(3) . Why?

Explain why aniline is less basic than methylamine ?

(A) Phenols are acidic & react with alkalies like NaOH but do not react with Na_2CO_3 and NaHCO_3 solutions (R) CO_3^(-2) & HCO_3^- ions are less basic than phenoxide ion