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Give reason. In case of optically active...

Give reason. In case of optically active alkyl halides, SN1 reactions are accompanied by racemisation

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Since the carbocation is planar
or
`sp^(2)` hybrid carbocation
or
Nucleophile can attack the carbocation from both the sides.
The carbocation has `sp^(2)`-hybrid carbon atoms with planar structure. Thus, nucleophile can attack from both the sides equally to for d and l-isomers in equal proportional.
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Comprehension The first demonstration of the stereochemistry of the S_(N^2) reaction was carried out in 1934 by Prof. E.D Hughes and his colleagues at the University of London. They allowed (R) -2- iodooctane to react with radioactive iodide ion (""^(**)I-) The rate of substitution (rate constant K_5 ) was determined by measuring the rate of incorporation of radioactivity into the alkyl halide. The rate of loss of optical acitivity from the alkyl halide (rate constant K_0 ) was also determined under the same conditions: What ratio K_0//K_s is predicted for each of the following stereochemical scenarios : For inversion reaction :

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