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Diborane react with ammonia under differ...

Diborane react with ammonia under different conditions to give a variety of products. Which one among the following is not formed in these reactions

A

`B_(2)H_(6).2NH_(3)`

B

`B_(12)H_(12)`

C

`B_(3)N_(3)H_(6)`

D

`(BN)_(n)`

Text Solution

Verified by Experts

The correct Answer is:
B
`B_(2)H_(6)+2NH_(2)overset(" low temp "(120^(@)C))rarr B_(2)H_(6).2NH_(3)`
`3B_(2)H_(6)+6NH_(3)overset(200^(@)C)rarr 2B_(3)N_(3)H_(6)+12H_(2)`
`B_(2)H_(6)+NH_(3)overset(" very high temp ")rarr (BN)_(n)`
`therefore B_(12)H_(12)` is not formed.
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