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The geometry of H(2)S and its dipole mom...

The geometry of `H_(2)S` and its dipole moment are

A

Angular and non-zero

B

Angular and zero

C

Linear and non-zero

D

Linear and zero

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The correct Answer is:
A
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Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic character is due to shifting of the electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic character is described as polar covalent bond. Polar covalent molecules can exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of molecules depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moments help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis-and traps-isomers, ortho-, meta-and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula : % " ionic character " = ("Experimental value of dipole moment ")/("Theoretical value of dipole moment ") xx 100 A diatomic molecule has a dipole moment of 1.2 D. If the bond length is 1.0 xx 10^(-8) cm, what fraction of charge does exist on each atom?

Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic character is due to shifting of the electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic character is described as polar covalent bond. Polar covalent molecules can exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of molecules depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moments help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis-and traps-isomers, ortho-, meta-and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula : % " ionic character " = ("Experimental value of dipole moment ")/("Theoretical value of dipole moment ") xx 100 Arrange the following compounds in increasing order of dipole moments, toluene (I), o- dichlorobenzene (II), m-dicblorobenzene (III) and p dichlorobenzene (IV) :

Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic character is due to shifting of the electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic character is described as polar covalent bond. Polar covalent molecules can exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of molecules depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moments help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis-and traps-isomers, ortho-, meta-and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula : % " ionic character " = ("Experimental value of dipole moment ")/("Theoretical value of dipole moment ") xx 100 The dipole moment of NF_(3) is very much less than that of NH_(3) because :

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No. of compounds having net dipole moment are

AAKASH SERIES-CHEMICAL BONDING-OBJECTIVE EXERCISE-2B
  1. Which of the following will have zero dipole moment?

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  2. The molecules BF3 and NF3 are covalent compounds. But BF3 is non-pol...

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  3. Which of the following has highest dipole moment?

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  4. BeF2 has zero dipole moment where as H2 Ohas a dipole moment because

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  5. Molecule with dipole moment among the following

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  6. Which of the following has highest dipole moment?

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  7. A molecule MX3 has zero dipole moment. The % of's' character in the h...

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  8. A diatomic molecule has a dipole moment 1.2D. If the internuclear dist...

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  9. The C-H bond distance is largest in

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  10. In compounds of type ECl3, where E = B, P, As or Bi, the angles CI-E -...

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  11. The geometry of H(2)S and its dipole moment are

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  12. In O(2), H(2)O(2) and O(3) the correct order of oxygen -oxygen bond le...

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  13. The correct order of bond lengths is

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  14. Bone energy is least in the following

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  15. Which of the following statements is incorrect ?

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  16. Bond length of H2 is 0.074nm, Bond length of Cl2 is 1.98A^@. Bond leng...

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  17. Average C-H energy is 416 KJ.mol^(-1) Which of the following is correc...

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  18. The decreasing order of bond dissociation energies of C-C, C-H and H-H...

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  19. The highest dipolemoment is of

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  20. The correct order of N-O bond length in No, NO(2)^(-) and NO(3)^(-) wi...

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