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Aniline is less basic than...

Aniline is less basic than

A

`NH_(3)`

B

`CH_(3)NH_(2)`

C

N-methyl Aniline

D

All the above

Text Solution

Verified by Experts

The correct Answer is:
D
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Account for the following : (a) (CH_(3))_(2)NH is a stronger base than NH_(3) (b) CH_(3)CH_(2)NH_(2) is more basic than CH_(3)CONH_(2) (c) Aniline is less basic than Ethyl amine (d) On sulphonation of aniline, p-amino benzene sulphonic acid is formed.

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Knowledge Check

  • Which of the following is more appropriate reason of aniline being less basic than aliphatic amines ?

    A
    hyper conjugation
    B
    Steric hindrance
    C
    Delocalisation of lone pair
    D
    Negative inductive effect of `-NH_(2)` group

  • (A): Cyclohexanamine. is more basic than aniline. (R): pK_(b) of cyclohexanamine is less than that of aniline.

    A
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    B
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    C
    A is true, R is false
    D
    A is false, R is true

  • (A) Acetate ion is less basic than methoxide ion. (R) Acetate ion is resonance stabilised while methoxide ion doesn't show resonance.

    A
    Both (A) and (R) are true and (R) is the correct explanation of (A)
    B
    Both (A) and (R) are true and (R) is not the correct explanation of (A)
    C
    (A) is true but (R) is false
    D
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