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Aniline is less basic than...

Aniline is less basic than

A

`NH_(3)`

B

`CH_(3)NH_(2)`

C

N-methyl Aniline

D

All the above

Text Solution

Verified by Experts

The correct Answer is:
D
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Explore conceptually related problems

Account for the following : (a) (CH_(3))_(2)NH is a stronger base than NH_(3) (b) CH_(3)CH_(2)NH_(2) is more basic than CH_(3)CONH_(2) (c) Aniline is less basic than Ethyl amine (d) On sulphonation of aniline, p-amino benzene sulphonic acid is formed.

Which of the following is more appropriate reason of aniline being less basic than aliphatic amines ?

(A): Cyclohexanamine. is more basic than aniline. (R): pK_(b) of cyclohexanamine is less than that of aniline.

Tl(OH)_3 is less basic than TlOH . Why ?

(A) Acetate ion is less basic than methoxide ion. (R) Acetate ion is resonance stabilised while methoxide ion doesn't show resonance.

How many statements are correct of the following compounds I is more basic than IV, III is more basic than IV, III is less basic than IV, I is more basic than II. II is more basic than I and IV, II is more basic than I, III and IV.

IIA group metal oxides are less basic than IA group metal oxides because

(A): Aq. Na_(2)CO_(32) solution is more basic than that of aq. NaHCO_(3) . (R): The extent of hydrolysis of Na_(2)CO_(3) is less than that of NaHCO_(3)

Phenol is more acidic than water and methanol is less acidic than water

(A) Phenols are acidic & react with alkalies like NaOH but do not react with Na_2CO_3 and NaHCO_3 solutions (R) CO_3^(-2) & HCO_3^- ions are less basic than phenoxide ion

Knowledge Check

  • Which of the following is more appropriate reason of aniline being less basic than aliphatic amines ?

    A
    hyper conjugation
    B
    Steric hindrance
    C
    Delocalisation of lone pair
    D
    Negative inductive effect of `-NH_(2)` group

  • (A): Cyclohexanamine. is more basic than aniline. (R): pK_(b) of cyclohexanamine is less than that of aniline.

    A
    Both A & R are true, R is the correct explanation of A
    B
    Both A & R are true, R is not correct explanation of A
    C
    A is true, R is false
    D
    A is false, R is true

  • (A) Acetate ion is less basic than methoxide ion. (R) Acetate ion is resonance stabilised while methoxide ion doesn't show resonance.

    A
    Both (A) and (R) are true and (R) is the correct explanation of (A)
    B
    Both (A) and (R) are true and (R) is not the correct explanation of (A)
    C
    (A) is true but (R) is false
    D
    Both (A) and (R) are false