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A, B, C are with molecular formula C(8)H...

A, B, C are with molecular formula `C_(8)H_(11)N` three isomeric amines. A and B react with `CHCl_(3)+KOH` but not C. C reacts with `NaNO_(2)+HCl` to give yellow oily liquid. A and B on treatment with `Br_(2)` and acetic acid separately produced compounds D `(C_(8)H_(9)NBr_(2))` and `E(C_(8)H_(8)N Br_(3))`.
The name of compound B is likely to be

A

3, 4 – dimethyl aniline

B

3, 5 – dimethyl aniline

C

4 – Ethyl aniline

D

2, 6 – dimethyl aniline

Text Solution

Verified by Experts

The correct Answer is:
D
A, B are `1^(@)` amines, .C. `2^(@)` amine
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Knowledge Check

  • A, B, C are with molecular formula C_(8)H_(11)N three isomeric amines. A and B react with CHCl_(3)+KOH but not C. C reacts with NaNO_(2)+HCl to give yellow oily liquid. A and B on treatment with Br_(2) and acetic acid separately produced compounds D (C_(8)H_(9)NBr_(2)) and E(C_(8)H_(8)N Br_(3)) . compound A is

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    B
    C
    D
    All the above

  • A, B, C are with molecular formula C_(8)H_(11)N three isomeric amines. A and B react with CHCl_(3)+KOH but not C. C reacts with NaNO_(2)+HCl to give yellow oily liquid. A and B on treatment with Br_(2) and acetic acid separately produced compounds D (C_(8)H_(9)NBr_(2)) and E(C_(8)H_(8)N Br_(3)) . compound C may be

    A
    B
    C
    D
    All the above

  • An organic compound with molecular formula C_(3)H_(5)N on hydrolysis gives an acid. The acid on heating with N_(3)H and conc. H_(2)SO_(4) gives

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