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The isomeric compounds ‘A’ and 'B' with ...

The isomeric compounds ‘A’ and 'B' with molecular fomula `C_(7)H_(9)N` gave the following reactions. When B is acetylated and then brominated, it gave one monobromo derivative. 'A' when treated with `NaNO_(2)` and HCI gave the compound 'C'. 'C' was heated with acetic acid in the presence of conc. `H_(2)SO_(4)`, a pleasant smelling liquid (D) was obtained. 'B' was treated with Na
‘B’ is

A

benzylamine

B

p-toluidine

C

o-toluidine

D

m-toluidine

Text Solution

Verified by Experts

The correct Answer is:
B
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An organic compound (A) with molecular formula C_(6)H_(7)N gives (B) with HNO_(2)//HCl at 273 K. The aqueous solution of (B) on heating gives compound (C) which gives violet colour with neutral FeCl3. Identify the compounds A, B and C and write the equations.

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Knowledge Check

  • Which of the following compounds is formed when ethanol reacts with acetic acid in the presence of concentrated H_(2) SO_(4)

    A
    `CH_(3) CO OC_(2) H_(5)`
    B
    `C_(2) H_(5) O C_2 H_5`
    C
    `CH_(3) O CH_(3)`
    D
    `CH_(3) CH_(2) CHO`

  • Which of the following compound is formed when ethanol reacts with acetic acid in the presence of concentrated H_2 SO_4 .

    A
    `CH_3 COOC_2 H_5`
    B
    `C_2 H_5 OC_2 H_5`
    C
    `CH_3 O CH_3`
    D
    `CH_3 CH_2 CHO`

  • Heating a mixture of ethyl alcohol acetic acid in presence of conc. H_2SO_4 produces a fruity smelling compounds A . Then A is

    A
    Ether
    B
    Ester
    C
    Aldehyde
    D
    Ketone

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