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In the spectrum of hydrogen atom, the ra...

In the spectrum of hydrogen atom, the ratio of the longest wavelength in Lyman series to the longest wavelangth in the Balmer series is

A

`(27)/(5)`

B

`(5)/(27)`

C

`(4)/(9)`

D

`(9)/(4)`

Text Solution

Verified by Experts

The wavelength of a spectral line in the Lyman series is
`(1)/(lambda_(L))=R((1)/(1^(2))-(1)/(n^(2))),n=2,3, 4, …………..`
and that in the Balmer series is
`(1)/(lambda_(B))=R((1)/(2^(2))-(1)/(n^(2))),n=3,4, 5,…………`
For the longest wavelength in the Lyman series, `n= 2`
`therefore" "(1)/(lambda_(L))=R((1)/(1^(2))-(1)/(2^(2)))=R((1)/(1)-(1)/(4))=R((4-1)/(4))=(3R)/(4)`
`or lambda_(L)=(4)/(3R)`
For the longest wavelength in the Balmer series, n = 3
`therefore" "(1)/(lambda_(B))=R((1)/(2^(2))-(1)/(3^(2)))=R((1)/(4)-(1)/(9))=R((9-4)/(36))=(5R)/(36)`
`"or "lambda_(B)=(36)/(5R)`
Thus, `(lambda_(L))/(lambda_(B))=((4)/(3R))/((36)/(5R))=(4)/(3R)xx(5R)/(36)=(5)/(27)`
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