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Ionisation of boric acid in aqusous med...

Ionisation of boric acid in aqusous medium gives which one of the following?

A

`[B(OH)_(4)]^(-)`

B

`[B(OH)_(2)O]^(-)`

C

`[B(OH)O_(2)]^(2-)`

D

`[BO_(3)]^(3-)`

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The correct Answer is:
To solve the question regarding the ionization of boric acid in an aqueous medium, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Chemical Formula of Boric Acid**: - The chemical formula of boric acid is \( H_3BO_3 \). It can also be represented as \( B(OH)_3 \). 2. **Understand the Ionization Process**: - When boric acid is dissolved in water, it undergoes hydrolysis. This means it reacts with water to form other species. 3. **Write the Hydrolysis Reaction**: - The hydrolysis of boric acid can be represented by the following reaction: \[ B(OH)_3 + H_2O \rightleftharpoons B(OH)_4^- + H_3O^+ \] - In this reaction, boric acid accepts a hydroxide ion (\( OH^- \)) from water, leading to the formation of the tetrahydroxyborate ion (\( B(OH)_4^- \)) and hydronium ion (\( H_3O^+ \)). 4. **Determine the Nature of Boric Acid**: - Boric acid is classified as a Lewis acid because it does not donate protons (\( H^+ \)) directly; instead, it accepts hydroxide ions. 5. **Identify the Correct Answer**: - From the hydrolysis reaction, we can see that the product formed is \( B(OH)_4^- \). Therefore, the correct answer to the question is the species \( B(OH)_4^- \). ### Final Answer: The ionization of boric acid in an aqueous medium gives \( B(OH)_4^- \). ---
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