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In cubic ZnS (II-VI) compounds, if the r...

In cubic `ZnS (II-VI)` compounds, if the radii of `Zn` and `S` atoms are `0.74 Å` and `1.70 Å`, the lattice parameter of cubic `ZnS` is

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In the zinc blende structure, zinc ions occupy alternate tetrahedral voids and S^(2-) ions exist as ccp the radii of Zn^(2+) and S^(2-) ions are 0.83Å and 1.74 Å respectively.The edge length of the ZnS unit cell is :

In the zinc blende structure, zinc ions occupy alternate tetrahedral voids and S^(2-) ions exist as ccp the radii of Zn^(2+) and S^(2-) ions are 0.83Å and 1.74 Å respectively.The edge length of the ZnS unit cell is :

The crystal structure of Zinc blende (ZnS) consists of cubic close-packed (ccp) array of S^(2-) ions. If the radii of Zn^(2+)andS^(2-) ions are 0.74 and 1.84Å respectively, then which type of voids (tetrahedral or octahedral) formed in ccp array of S^(2-) ions are occupied by Zn^(2+) ions? What fraction of total number of this void remains unoccupied?