Home
Class 12
CHEMISTRY
The magnetic behaviour of complexes K4[F...

The magnetic behaviour of complexes `K_4[Fe(CN)_6]` and `K_3[Fe(CN)_6]` is

A

Para, Dia

B

Dia, Para

C

Dia, Ferro

D

Both Dia

Text Solution

Verified by Experts

The correct Answer is:
B
Promotional Banner

Topper's Solved these Questions

  • COMPLEX COMPOUNDS

    AAKASH SERIES|Exercise Objective Exercise-2|110 Videos
  • COMPLEX COMPOUNDS

    AAKASH SERIES|Exercise Objective Exercise-3 (PREVIOUS NEET/AIPMT)|46 Videos
  • COMPLEX COMPOUNDS

    AAKASH SERIES|Exercise SUBJECTIVE EXERCISE-5 (Very Short Answer)|7 Videos
  • CO-ORDINATION COMPOUNDS

    AAKASH SERIES|Exercise PRACTICE SHEET - 5 ( Linked Comprehension type questions Passage : I I:)|3 Videos
  • D & F BLOCK ELEMENTS

    AAKASH SERIES|Exercise PRACTICE SHEET-5 (INTEGER ANSWER TYPE QUESTIONS)|6 Videos

Similar Questions

Explore conceptually related problems

K_3[Fe(CN)_6] is a

K_(4)[Fe(CN)_(6)] is a

H_2O_2 reduce K_3 [Fe(CN)_6] in :

The name of complex ion [Fe(CN)_6]^(3-) is

Define EAN. Calculate the EAN of the following metals in their respective complexes: [Cu(NH_3)_4](OH)_2 and K_4[Fe(CN)_6]

Assertion: [Fe(CN)_6]^(3-) is weakly paramagnetic while [Fe(CN)_6]^(4-) is diamagnetic Reason: Both [Fe(CN)_6]^(3-) and [Fe(CN)_6]^(4-) involve d^2sp^3 hybridisation. In [Fe(CN)_6]^(3-) singly occupied d-orbital is available but in [Fe(CN)_6]^(4-) paired electrons are present

Valence bond theory successfully explains the magnetic behaviour of complexes. The substances which contains unpaired electrons are paramagnetic and paramagnetic character increases as the number of unpaired electrons increases. Magnetic moment of a complex can be determined experimentally and by using formula sqrt(n(n+2)) and we can determine the number of unpaired electrons in it. This information is important in writing electronic structure of complex which in turn also useful in deciding the geometry of complex. Which of the following are diamagnetic ? 1) K_(4)[Fe(CN)_(6)] 2) K_(3)[Cr(CN)_(6)] 3) K_(3)[Co(CN)_(6)] 4) K_(2)[Ni(CN)_(4)]

The bonds present in K_4 [Fe(CN)_6 ] are

The primary valency of 'Fe' in the complex K_(4)[Fe(CN)_(6)] is

AAKASH SERIES-COMPLEX COMPOUNDS -Objective Exercise-1
  1. For the same metal, stabilisation energies of tetrahedral and octahedr...

    Text Solution

    |

  2. Both [Ni(CO)4] and [Ni(CN)4]^(2-) , are diamagnetic. The hybridization...

    Text Solution

    |

  3. The magnetic behaviour of complexes K4[Fe(CN)6] and K3[Fe(CN)6] is

    Text Solution

    |

  4. Which one of the following cyano complexes exhibit the lowest value of...

    Text Solution

    |

  5. The hybridisation of nickel in tetracarbonyl nickel is

    Text Solution

    |

  6. The oxidation state of the metal forming the complex K2[PtCl6] is

    Text Solution

    |

  7. In the complex [Ni(H2O)2 (NH3)4]^(2+) the number of unpaired electron...

    Text Solution

    |

  8. The correct order of increasing field strengths

    Text Solution

    |

  9. In which of the following octahedral complexes of cobalt (atomic numbe...

    Text Solution

    |

  10. According to crystal field theory, the M-L bond in a complex is

    Text Solution

    |

  11. The number of unpaired electron in [Pt(CN)4]^(2-) ion having square pl...

    Text Solution

    |

  12. Which one of the following is square planar in structure and has diama...

    Text Solution

    |

  13. [Cr(H2O)6]Cl3 and [Cr(H2O)4Cl2]Cl. H2O are hydrate isomers. Their colo...

    Text Solution

    |

  14. Which of the following does not has an optical isomer?

    Text Solution

    |

  15. Which of the following has an optical isomer ?

    Text Solution

    |

  16. Which of the following pairs represents linkage isomers ?

    Text Solution

    |

  17. Which of the following will exhibit geometrical isomerism? (M stands f...

    Text Solution

    |

  18. The ionization isomer of [Cr(H2O)4 Cl(NO2)]Cl is given as

    Text Solution

    |

  19. Ionisation isomerism is possible with

    Text Solution

    |

  20. [PtBrCl(NO(2))(NH(3))] I on ionisation gives the ion

    Text Solution

    |