If Delta0 lt P , the correct electronic ...

If `Delta_0 lt P` , the correct electronic configuration for `d^4` system will be

`t_(2g)^4 e_g^0`

`t_(2g)^3 e_g^1`

`t_(2g)^0 e_g^4`

`t_(2g)^2 e_g^2`

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If Delta_0 gt P the correct electronic confuguration for d^4 system will be

In octahedral complexes having co-ordination number 6, the degeneracy of the d-orbitals of central atom is removed due to ligand electron metal electron repulsions. In the octahedral complex three orbitals have lower energy, t_(2g) set and two orbitals have higher energy, eg set. This phenomenon is formed as crystal field splitting and the energy seperation is denoted by Delta_(0) . Thus the energy of the two eg orbitals will increase by (3//5)Delta_(0) and that of the three t_(2g) will decrease by (2//5)Delta_(0) . The erystal field splitling, Delta_(0) depends upon the field produced by the ligand and charge on the metal ion. Some ligands are able to produce strong field and in these cases, the splitting will be large whereas other produce weak fields and consequently result in small splitting of d-orbitals. If Delta_(0)ltP , the correct electronic configuration of d^(4) system will be

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AAKASH SERIES-COMPLEX COMPOUNDS -Objective Exercise-2

Crystal field theory does not explain which of the following property ...
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Indicate the hydbridisation and Magnetic nature of Ni(CO)4
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Which of the following are true for the complex Ni(CN)4^(2-) ion (A...
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Which one of the following ionic species will impart colour to an aque...
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The spin only magnetic moment [Mn(Br)4]^(2+) is 5.9BM. Then possible ...
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Match the following
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The correct statement regarding [Co(C2O4)3]^(3+) complex is
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The complex K3[Fe(CN)6] should have a spin only magnetic moment of
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The IUPAC name of the coordination compound K3[Fe(CN)6]
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When AgNO3 solution is added in excess to 1M solution of CoC13 cx NH3 ...
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The hypothetical complex chlorodiaquatriam minecobalt (III) chloride c...
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The IUPAC name of [Co(NH3)4Br2]^+ [ZnCl4]^(-) is
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