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Explain the following: a) why the boil...

Explain the following:
a) why the boiling points of primary amines are higher than those of the corresponding tertiary amines of similar molar mass.
b) why aromatic amines are lesser basic than aliphatic amines ?
c) why alcohols are more acidic than amines of comparable molar mass?
d) Gabriel phthalimide synthesis is not useful in the preparation of aromatic primary amines?

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