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Which compound will not give positive ch...

Which compound will not give positive chronyl chloride test:

A

Copper chloride `CuCl_(2)`

B

Mercuric chloride, `HgCl_(2)`

C

Zinc chloride, `ZnCl_(2)`

D

Anilinium chloride, `C_(6)H_(5)NH_(3)^(+)Cl^(-)`

Text Solution

Verified by Experts

The correct Answer is:
B
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An alcohol (A) on dehydration gives (B) which on ozonolysis gives two products C & D (D) gives positive iodoform test and on heating with dilute alkali gives alpha . beta -unsaturated carbonyl compound (E) which does not gives positive iodoform test. (C) on oxidation gives a mono basic acid (F) Ag salt of (F) contains 59.6% Ag. Oxime of (D) contains 16.09% nitrogen. the structure of (E ) is given reaction is