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An aqueous solution of a white salt A gi...

An aqueous solution of a white salt A gives a white precipitate B on treatment with dilute HCI in cold conditions. B is soluble in boiling water. An aqueous solution of A gives a yellow precipitate on treatment with a solution of `K_(2)CrO_(4)`. The soda extract of A is acidified with dilute `H_(2)SO_(4)` boiled to remove `CO_(2)` and treated with a freshly prepared solution of `FeSO_(4)` Concentrated `H_(2)SO_(4)` is added to the resulting solution (along the walls of the test tube so that the `H_(2)SO_(4)` forms a separate layer). A brown ring is formed at the junction of the two layers.
On treatment with a Kl solution, an aqueous solution of A will give

A

a white precipitate soluble in an excess of `NH_(3)`

B

a white precipitate soluble in an excess of `NH_(3)`

C

a grey precipitate soluble in an excess of `NH_(3)`

D

a grey precipitate insoluble in an excess of `NH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
B

A white precipitate soluble in excess of `NH_(3)`
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