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(i) A white solid A, on being strongly h...

(i) A white solid A, on being strongly heated, leaves a residue which is yellow while hot and white when cold
ii) The solid A, insoluble in water, dissolves in dilute HCI to give a solution B and a gas which does not affect acidified dichromate paper but turns baryta water milky.
iii) When `H_(2)S` is passed through the solution B, a white precipitate C is obtained
iv) The precipitate C dissolves in dilute HCI to give a solution which, when treated with an NaOH solution, gives a white precipitate. The final precipitate dissolves in an excess of NaoH form a solution D. This alkaline solution, on acidification with acetic acid followed by treatment with `H_(2)S`, gives the precipitate C.
Given that the formation of the precipitate C from the solution D involves the reaction
`[M(OH)_(4)]^(2-)+4H^(+) to underset(underset(MS darr)(darr H_(2)S))(M^(2+))+4H_(2)O`
M is

A

Zn

B

Al

C

Pb

D

Sn

Text Solution

Verified by Experts

The correct Answer is:
A

Zinc
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