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(1) Chlorine forms number of oxides such...

(1) Chlorine forms number of oxides such as `Cl_(2)O , ClO_(2), Cl_(2) O_(7)` chlorine and oxygen donot combine together directly. So, these are prepared by indirect method.
`HgO. Hgo + Cl_(2) rarr Cl_(2)O + Hg ` ,
(2) Some of these oxides undergo disproportionation reactions.
For Ex `: Cl_(2) O_(6) + 2KOH rarr KClO_(3) + KClO_(4) + H_(2)O`
( 3) The oxides of chlrine are acidic in nature. `Cl_(2)O_(7)` is the anhydride of perchloric acid
`Cl_(2) O_(7) + H_(2) O rarr 2HClO_(4)`
Which of the given statement is incorrect

A

`ClO_(3)` exists in equilibrium with `Cl_(2) O_(6)` the dimer diamagnetic while monomer is paramagnetic

B

`Cl_(2)O` is an angular molecule

C

`Cl_(2) O_(6)` is mixed anhydride of chloric acid & perchloric acid

D

`ClO_(2)` reacts with KOH to give a mixture of `Cl_(2)` & `KClO_(2)`

Text Solution

Verified by Experts

The correct Answer is:
D
`2ClO_(2) + 2KOH rarr KClO_(2) + KClO_(3) + H_(2)O`
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(1) Chlorine forms number of oxides such as Cl_(2)O , ClO_(2), Cl_(2) O_(7) chlorine and oxygen donot combine together directly. So, these are prepared by indirect method. HgO. Hgo + Cl_(2) rarr Cl_(2)O + Hg , (2) Some of these oxides undergo disproportionation reactions. For Ex : Cl_(2) O_(6) + 2KOH rarr KClO_(3) + KClO_(4) + H_(2)O ( 3) The oxides of chlrine are acidic in nature. Cl_(2)O_(7) is the anhydride of perchloric acid Cl_(2) O_(7) + H_(2) O rarr 2HClO_(4) Euochlorine is a mixture prepared by heating KClO_(3 with con HCl euchlorine is a mixture of

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In the reaction : Cl_2 + OH^(-) rarr Cl^(-) +ClO_(4)^(-) +H_(2)O chlorine is :

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