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Which of the following facts are true ?...

Which of the following facts are true ?

A

If `E^(0)(M^(n+)//M)` is negative , `H^(+)` will be reduced to `H_2` by the metal M.

B

If `E^(0) (M^(n+)//M)` is positive , `M^(n+)` will be reduced to M by `H_2`

C

In a cell , `M^(n+)//M` assembly is attached to hydrogen -half cell. To produce spontaneou cell reaction, metal M will act as negative electrode if the potential `M^(n+)//M` is negative. It will serve as positive electrode , if `M^(n+)//M` has a positive cell potential.

D

Compound of active metal (Zn,Na, Mg) are reducible by `H_2` where as those of noble metals (Cu , Ag , Au) are not reducible

Text Solution

Verified by Experts

The correct Answer is:
A, B, C

a) `2H^(+) + 2e^(-) overset("red")to H_2 , "b)" M^(n+) + n e^(-) overset("red")to M`
c) `M^(n+)//M` assembly attached to hydrogen half cell
To produce spotaneous cell reaction
M ` to -ve` electrode , `M^(n+)//M` is negative
It acts as +ve electrode , if `M^(n+)//M` has positive cell potential
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AAKASH SERIES-ELECTROCHEMISTRY -LEVEL-II (LECTURE SHEET ( EXERCISE -I ( SINGLE & ONE OR MORE THAN ONE CORRECT ANSWER )))
  1. The cell emf depends on

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  2. The cell emf in a cell with cell reaction Cr2O7^(2-) + 14H^(+) + 6Fe^(...

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  3. Which of the following facts are true ?

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  4. In a lead storage battery

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  5. Which one is correct among the following give, the half cell emf's E^...

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  6. For the cell (at 298 K ) Ag((g)) // AgCl((s)) // Cl((aq))^(-) ||AgNO(3...

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  7. The value of the reaction quotient ,Q for the cell Zn(s) |Zn^(2+) (0.0...

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  8. DeltaG = DeltaH-TdeltaS and DeltaG = DeltaH + T[(d(DeltaG))/(dT)] " ...

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  9. For the cell Zn|Zn^(2+) (C1)||Zn^(2+) (C2)|Zn. DeltaG is negative if :

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  10. The Nernst equation , E = E^(0) -(RT)/(nF) . In Q indicates that the ...

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  11. The half cell reaction for the corrosion are , 2H^(+) + (1)/(2) O2 + ...

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  12. The E^(@) at 25^(@)C for the following reaction at the indicated conc...

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  13. A fuel cell develops an electrical potential from the combustion of b...

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  14. For a cell reaction 2H(2(g)) + O(2(g)) to 2H2O((l)) DeltaS(298)^(@) ...

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  15. Copper reduces NO3^(-) into NO and NO2 depending upon concentration of...

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  16. Consider the following standard reduction potentials Fe^(3+)(aq) + e...

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  17. Which of the following statements is / are correct ?

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  18. Which of the following facts regarding the movement of anions in the s...

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  19. Which of the following statements is correct ? If E(Cu^(2+)|Cu)^(@)...

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  20. The oxidation potential of hydrogen half-cell will be negative if :

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