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The chain terminating groups like -COOH ...

The chain terminating groups like -COOH - CHO, -CN, etc. should always get the number '1' for the carbon atom

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When an electron withdrawing or electron releasing group is attached to carbon chain, polarity is induced on the carbon atom and on the substituent attach to it. This permanent polarity is due electron displacement due to difference in electronegativities this is called inductive effect or I effect. The inducitve effect depends in the electronegativity of the substituent. The inductive effect is broadly classified as (i) negative inductive effect or -I effect. (ii) positive inductive effect or +I effect. The group which exhibits the maximum -I effect

When an electron withdrawing or electron releasing group is attached to carbon chain, polarity is induced on the carbon atom and on the substituent attach to it. This permanent polarity is due electron displacement due to difference in electronegativities this is called inductive effect or I effect. The inducitve effect depends in the electronegativity of the substituent. The inductive effect is broadly classified as (i) negative inductive effect or -I effect. (ii) positive inductive effect or +I effect. Which of the following statements is correct about inductive effect ?

When an electron withdrawing or electron releasing group is attached to carbon chain, polarity is induced on the carbon atom and on the substituent attach to it. This permanent polarity is due electron displacement due to difference in electronegativities this is called inductive effect or I effect. The inducitve effect depends in the electronegativity of the substituent. The inductive effect is broadly classified as (i) negative inductive effect or -I effect. (ii) positive inductive effect or +I effect. Stability of given anions in the decreasing order is (i) bar(C)H_(3) " (ii) "bar(C)H_(2)-NO_(2)" (iii) "bar(C)H_(2)Cl" (iv) "CH_(3)-bar(C)H_(2)

Hydrogen bonding is said to be formed, -when sightly acidic hydrogen-atom attached to a strongly, electronegative fluorine, oxygen or nitrogen atom. is held with weak. electrostatic forces by the non-bonded pair of electrons of another atom. The co-ordination number of hydrogen in such cases is two. It acts as a bridge between two atoms, to one of which it is covalently bonded and to other attached through electrostatic forces, also called hydrogen bond. Though the hydrogen atoms in a methyl group are not polarised, if an electronegative group like chloro, carbonyl, nitro or cyano (in order to increase electronegativity) is attached to it, the C-H bond gets polarised due to the inductive effect and the hydrogen atom becomes slightly acidic resulting in the formation of weak hydrogen bonds. Though a weak bond the H-bond effects is large number of the physical properties of compounds some of which are - Boiling points of liquids - Solubility of polar compounds in polar solvents (containig H attached with strong electronegative atom) - Viscosity of liquids . Acidity Which of the following combinations can involve hydrogen bonding I) Mixture of KF and HF " " II) Mixture of CH_(3)COCH_(3) and CHCI_(3) III) Mixture of NH_(4) CI and H_(2)O" " IV) Mixture of CH_(3) and H_(2)O

AAKASH SERIES-GENERAL ORGANIC CHEMISTRY-Subjective Exercise -8
  1. If a number of groups are attached to the partent chain, the name is g...

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  2. The order of decreasing priority for functional groups is carboxylic a...

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  3. The chain terminating groups like -COOH - CHO, -CN, etc. should always...

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  4. When a benzene ring is attached to an alkane with a functional group, ...

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  5. Compounds having the same molecular formula, same structure with diffe...

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  6. Compounds having the same molecular formula, same structure with diffe...

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  7. Structural isomerism is due to the difference in the linkage of atoms ...

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  8. Structural isomerism is divided into chain, position, function group m...

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  9. Stereoisomerism is due to the difference in arrangement of atoms or gr...

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  10. Stereo isomers have same molecular formula but differ in the spatial a...

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  11. Chain isomerism arises due to difference in the arrangement of carbon ...

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  12. Chain isomers differ in the nature of the carbon chain (skeleton)

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  13. Butane has 2 chain isomers: pentane has 3, hexane has 5 and heptane ha...

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  14. Position isomerism is due to the difference in the position of a funct...

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  15. Compounds having same molecule formula but difference functional group...

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  16. Alchohol's ethers, aldehydes-ketones, carboxylic acids-esters, etc, ar...

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  17. Metamerism is due to the presence of different alkyl groups attached t...

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  18. Ketone secondary amines, ethers etc show metamerism

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  19. Tautomerism is a special type of functional isomerism where the isomer...

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  20. Configurational isomerism is further divided into geometrical isomeris...

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