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The order of +I effect is: (CH(3))C gt (...

The order of +I effect is: `(CH_(3))C gt (CH_(3))_(2) CH gt CH_(3)CH_(2) gt CH_(3)`

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CH_(3)CH_(2)C(O)NHCH_(2)CH_(2)CH_(3) is

Acidic nature order of some alcohol is CH_(3)OH gt CH_(3)CH_(2)OH gt (CH_(3))_(2) CHOH

The stability order of carbanions is: CH_(3)^(-) gt CH_(3)CH_(2)^(-) gt (CH_(3))_(2) CH^(-) gt (CH_(3))_(3) C^(-)

Explain the following order of strength of bases. (a) (CH_(3))_(2)NH gt CH_(3)NH_(2) gt NH_(3) (b) p-toluidine > Aniline > p-nitro aniline

Arrange the following compounds in increasing order of their boiling points. CH_(3)CHO, CH_(3)CH_(2)OH, CH_(3)OCH_(3), CH_(3)CH_(2)CH_(3)

Arrange the following compounds in increasing order of their boiling points. CH_(3)CHO, CH_(3)CH_(2)OH, CH_(2)OCH_(3), CH_(3)CH_(2)CH_(3)

The stability order of alkyl free radicals is: (CH_(3))_(3) overset(.)C gt (CH_(3))_(2) overset(.)CH gt CH_(3) overset(.)CH_(2) gt overset(.)CH_(3)

Bond energy : Energy required to break a bond (equal to the energy released when a bond is formed) is named bond energy. Its unit is Kcal/mole. Stability of bond energy 00 % s character oo(1)/(% "P character")oo "bond order" oo(1)/("bond length") Higher is the number of bonds at a place, higher is the bond energy. Which are true in terms of bond energy ? (i) CH_(3) -Fgt CH_(3) -Clgt CH_(3)- Brgt CH_(3)-1 (ii) H_(3) C - O lt H_(3) C - CH_(3) lt CH_(2) = CH -O - CH_(3) (iii) CH_(3) - CH_(2) -O - CH_(3) lt CH_(2) =CH-O -CH_(3) (iv) C- N gt N gt C = N (v) CH_(3) - CH_(2)- NH_(2) lt CH_(2) = CH -NH_(2) lt CH= C -NH_(2)

How can the following conversions be effected ? (a) CH_(3)COCl rarr CH_(3)CHO (b) CH_(3)COCl rarr CH_(3)COCH_(3) (c ) CH_(3)CN rarr CH_(3)CHO (d) CH_(3)CN rarr CH_(3)CH_(2)OH

AAKASH SERIES-GENERAL ORGANIC CHEMISTRY-Subjective Exercise -8
  1. The order of -I effect is NO(2) gt CN gt SO(3)H gt CHO gt CO gt COOH...

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  2. The atom or group which has less power to attract the electrons than h...

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  3. The order of +I effect is: (CH(3))C gt (CH(3))(2) CH gt CH(3)CH(2) gt ...

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  4. Inductive effect is a permanent effect and it tends to be insignifican...

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  5. Acidic nature order of various carboxylic acids and subsituted carboxy...

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  6. Phenol is more acidic than water and methanol is less acidic than wate...

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  7. Acidic nature order of some alcohol is CH(3)OH gt CH(3)CH(2)OH gt (CH(...

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  8. Relative strength of bases also can be explained by inductive effect

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  9. Due to steric effect tertiary amines may not be more basic than second...

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  10. Electromeric effect is the complete transfer of the shared pair of pi ...

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  11. Electromeric effect is a temporary effect and comes into play instanta...

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  12. When the transfer of electrons takes place towards the attacking reage...

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  13. When the transfer of electrons takes place waya from the attacking rea...

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  14. When both inductive and electronmeric effects simultaneously operate, ...

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  15. Mesomeric or resonance effect is a permanent effect involving the tran...

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  16. Electromeric effect always faciliates the reaction and never inhibits

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  17. Groups with +M effect increase the electron density of the rest of the...

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  18. Groups with -M effect decrease the electron density of the rest of the...

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  19. Resonance effect is called conjugative effect if it is transmitted thr...

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  20. The energy of actual structure of the molecule is lower than that of ...

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