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When both inductive and electronmeric ef...

When both inductive and electronmeric effects simultaneously operate, usually electromeric effect predominates

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Write a brief note on electromeric effect

Which of the following show electromeric effect?

Inductive effect refers to

Which of the following shows electromeric effect?

(A): Alkenes, carbonyl compounds can exhibit electromeric effect but not alkanes, saturated alcohols (R ): Electromeric effect is possible organic compounds having at least one multiple bond

Explain the terms Inductive and Electromeric effects. Which electron displacement effect explains the following correct orders of acidity of the carboxylic acids? (a) Cl_(3)C COOHgtCl_(2)CHCOOHgtClCH_(2)COOH (b) CH_(3)CH_(2)COOHgt(CH_(3))_(2)CHCOOHgt(CH_(3))_(2)C.COOH

How the strength of an acid changes with inductive and mesomeric effects exerted by various groups present in it.

Electrophilic substitution on mono substituted benzene is determined by electronic effects +1, -M groups are ortho, para directors, where as -1,-M groups are meta directions. When there is a competition between inductive and mesomeric effects, the latter wins over. Electrophilic substitution on disubstituted benzene is determined by the combined effect of both groups. Usually activating group wins over deactivating group. When one of the groups has a lone pair of electrons, that will determine the product formation. Usually a third group will not enter the position in between the two existing groups due to steric reasons. Identify the incorrect statement

Electrophilic substitution on mono substituted benzene is determined by electronic effects +1, -M groups are ortho, para directors, where as -1,-M groups are meta directions. When there is a competition between inductive and mesomeric effects, the latter wins over. Electrophilic substitution on disubstituted benzene is determined by the combined effect of both groups. Usually activating group wins over deactivating group. When one of the groups has a lone pair of electrons, that will determine the product formation. Usually a third group will not enter the position in between the two existing groups due to steric reasons. Major products of nitration of acetanilide is:

Electrophilic substitution on mono substituted benzene is determined by electronic effects +1, -M groups are ortho, para directors, where as -1,-M groups are meta directions. When there is a competition between inductive and mesomeric effects, the latter wins over. Electrophilic substitution on disubstituted benzene is determined by the combined effect of both groups. Usually activating group wins over deactivating group. When one of the groups has a lone pair of electrons, that will determine the product formation. Usually a third group will not enter the position in between the two existing groups due to steric reasons.

AAKASH SERIES-GENERAL ORGANIC CHEMISTRY-Subjective Exercise -8
  1. When the transfer of electrons takes place towards the attacking reage...

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  2. When the transfer of electrons takes place waya from the attacking rea...

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  3. When both inductive and electronmeric effects simultaneously operate, ...

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  4. Mesomeric or resonance effect is a permanent effect involving the tran...

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  5. Electromeric effect always faciliates the reaction and never inhibits

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  6. Groups with +M effect increase the electron density of the rest of the...

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  7. Groups with -M effect decrease the electron density of the rest of the...

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  8. Resonance effect is called conjugative effect if it is transmitted thr...

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  9. The energy of actual structure of the molecule is lower than that of ...

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  10. The difference between the real energy of the resonance hybrid structu...

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  11. Resonance explains the stability of aromatic compounds, some unusual b...

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  12. When alkyl groups are attached to an unsaturated system or a benzene n...

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  13. Hyperconjugation is also called sigma-pi conjugation or no bond resoan...

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  14. Grater the number of methyl groups attached to the double bonded carbo...

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  15. Stability of alkenes, carbocations, alkyl free radicals, orienting eff...

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  16. Homolytic fission of a covalent bond leads to the formation of neutral...

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  17. Homolytic fission is favoured by conditions such as non-polar nature o...

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  18. Heterolytic fission of a covalent bond leads to the formation of charg...

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  19. The Hetrolytic fission will be favoured by polar nature of the bond, ...

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  20. Carbocation is a group of atoms that contains a carbon atom bearing po...

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