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Carbocation is a group of atoms that con...

Carbocation is a group of atoms that contains a carbon atom bearing positive charge and has only six electrons on its valence shell

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Carbocations are species in which central carbon carries positive charge. If the charge on the carbocations gets cocentrated or lo-calized the carbocation becomes unstable. The two factors which account for stability of carbocations are inductive effect and hyper conjugation (no bond resonance). Inductive effect is minor factor and hyper conjugation is major factor. Hybridisation of carbon in carbocation is

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AAKASH SERIES-GENERAL ORGANIC CHEMISTRY-Subjective Exercise -8
  1. Heterolytic fission of a covalent bond leads to the formation of charg...

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  2. The Hetrolytic fission will be favoured by polar nature of the bond, ...

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  3. Carbocation is a group of atoms that contains a carbon atom bearing po...

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  4. The positively charged carbon atom in the carbocation is in sp^(2) hyb...

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  5. Order of stability of carbocations is: R(3)C^(+) gt R(2)overset(+)C H ...

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  6. The stability order can be explained by hyper conjugation and also by ...

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  7. Carbanion is a group of atoms that contains a carbon atom bearing nega...

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  8. The negatively charged carbon atom in the carbanion is in sp^(3) hybri...

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  9. The stability order of carbanions is: CH(3)^(-) gt CH(3)CH(2)^(-) gt (...

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  10. If an unpaired electron is present on a carbon atom in a group of atom...

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  11. Alkyl free radicals are planar and the central carbon atom is in sp^(2...

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  12. The unhybridised 2p orbitals of the central carbon atom of alkyl free ...

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  13. The stability order of alkyl free radicals is: (CH(3))(3) overset(.)C ...

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  14. The stability order of alkyl free radicals can be explained by hyperco...

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  15. Carbenes (: CH(2)) are neutral species in which carbon atom has six el...

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  16. Carbon atom in carbene is in sp^(2) hybridisation

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  17. Basing on the nature of the attacking site in the substrate, attacking...

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  18. Nucleophiles donate a free electron pair to the electron deficient cen...

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  19. Nucleophiles are either negatively charged or neutral

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  20. Cl^(-), Br^(-), I^(-), NH(2)^(-) , RNH^(-), R(2)N^(-), OR^(-), RCOO^(-...

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