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The unhybridised 2p orbitals of the cent...

The unhybridised 2p orbitals of the central carbon atom of alkyl free radical contains the unpaired electron

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AAKASH SERIES-GENERAL ORGANIC CHEMISTRY-Subjective Exercise -8
  1. If an unpaired electron is present on a carbon atom in a group of atom...

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  2. Alkyl free radicals are planar and the central carbon atom is in sp^(2...

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  3. The unhybridised 2p orbitals of the central carbon atom of alkyl free ...

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  4. The stability order of alkyl free radicals is: (CH(3))(3) overset(.)C ...

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  5. The stability order of alkyl free radicals can be explained by hyperco...

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  6. Carbenes (: CH(2)) are neutral species in which carbon atom has six el...

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  7. Carbon atom in carbene is in sp^(2) hybridisation

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  8. Basing on the nature of the attacking site in the substrate, attacking...

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  9. Nucleophiles donate a free electron pair to the electron deficient cen...

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  10. Nucleophiles are either negatively charged or neutral

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  11. Cl^(-), Br^(-), I^(-), NH(2)^(-) , RNH^(-), R(2)N^(-), OR^(-), RCOO^(-...

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  12. overset(..)(N)H(3), R overset(..)(N)H(2), R(2)NH, R(3) overset(..)(N),...

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  13. Electrophiles are electron deficient and attack the substrate where th...

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  14. Electrophiles are either positively charged or neutral

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  15. H^(+). Cl^(+), Br^(+), I^(+), NO(2)^(+), R(3)C^(+), NH(4)^(+), NO^(+),...

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  16. SO(3), BF(3), AlCl(3), FeCl(3), ZnCl(2), BeCl(2) etc., are neutral ele...

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  17. Nucleophiles act as Lewis bases and electrophiles act as Lewis acids

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  18. Ambiphiles are those species which behave like electrophiles and nucle...

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  19. In substitution reactions, an atom or a group attached to a carbon ato...

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  20. Substitution reactions are further classified as free radical, electro...

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