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The stability order of alkyl free radica...

The stability order of alkyl free radicals is: `(CH_(3))_(3) overset(.)C gt (CH_(3))_(2) overset(.)CH gt CH_(3) overset(.)CH_(2) gt overset(.)CH_(3)`

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The stability order of carbanions is: CH_(3)^(-) gt CH_(3)CH_(2)^(-) gt (CH_(3))_(2) CH^(-) gt (CH_(3))_(3) C^(-)

Order of stability of carbocations is: R_(3)C^(+) gt R_(2)overset(+)C H gt R overset(+)(CH_(2)) gt overset(+)(CH_(3))

Which of the following carbocation is most stable ? (a) (CH_(3))_(3)C.overset(+)(C )H_(2) (b) (CH_(3))_(3)overset(+)(C ) (c ) CH_(3)CH_(2)overset(+)(C )H_(2) (d) CH_(3)overset(+)(C )HCH_(2)CH_(3)

The order of +I effect is: (CH_(3))C gt (CH_(3))_(2) CH gt CH_(3)CH_(2) gt CH_(3)

Write the products in the following: CH_(3)-CH_(2)-CH_(2)-overset(CH_(3))overset(|)CH-CHO overset(NaBH_(4))to

CH_3 - overset(CH_3)overset(|)C = CH-CH_3 overset(Hg(OAc)_2 // EtOH)to underset((90%))((A)) .

Monomer is [-CH_(2)-underset(COOCH_(3))underset(|)overset(CH_(2))overset(|)(C)-]_(n) is

CH_3- overset(CH_3) overset(|) C=CH_2 overset(HCI) to CH_3 - underset(Cl) underset(|) overset(CH_3) overset(|) C-CH_3

Acidic nature order of some alcohol is CH_(3)OH gt CH_(3)CH_(2)OH gt (CH_(3))_(2) CHOH

Write the systematic name of CH_(3) - CH_(2) - overset(overset(O)(||))(C )-CH_(2) - overset(overset(O)(||))(C )-CH_(3)

AAKASH SERIES-GENERAL ORGANIC CHEMISTRY-Subjective Exercise -8
  1. Alkyl free radicals are planar and the central carbon atom is in sp^(2...

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  2. The unhybridised 2p orbitals of the central carbon atom of alkyl free ...

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  3. The stability order of alkyl free radicals is: (CH(3))(3) overset(.)C ...

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  4. The stability order of alkyl free radicals can be explained by hyperco...

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  5. Carbenes (: CH(2)) are neutral species in which carbon atom has six el...

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  6. Carbon atom in carbene is in sp^(2) hybridisation

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  7. Basing on the nature of the attacking site in the substrate, attacking...

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  8. Nucleophiles donate a free electron pair to the electron deficient cen...

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  9. Nucleophiles are either negatively charged or neutral

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  10. Cl^(-), Br^(-), I^(-), NH(2)^(-) , RNH^(-), R(2)N^(-), OR^(-), RCOO^(-...

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  11. overset(..)(N)H(3), R overset(..)(N)H(2), R(2)NH, R(3) overset(..)(N),...

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  12. Electrophiles are electron deficient and attack the substrate where th...

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  13. Electrophiles are either positively charged or neutral

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  14. H^(+). Cl^(+), Br^(+), I^(+), NO(2)^(+), R(3)C^(+), NH(4)^(+), NO^(+),...

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  15. SO(3), BF(3), AlCl(3), FeCl(3), ZnCl(2), BeCl(2) etc., are neutral ele...

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  16. Nucleophiles act as Lewis bases and electrophiles act as Lewis acids

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  17. Ambiphiles are those species which behave like electrophiles and nucle...

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  18. In substitution reactions, an atom or a group attached to a carbon ato...

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  19. Substitution reactions are further classified as free radical, electro...

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  20. Alkanes undergo free radical substitution, aromatic compounds undergo ...

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