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H^(+). Cl^(+), Br^(+), I^(+), NO(2)^(+),...

`H^(+). Cl^(+), Br^(+), I^(+), NO_(2)^(+), R_(3)C^(+), NH_(4)^(+), NO^(+), C_(6)H_(5)N_(2)^(+)` etc, are charged electrophiles

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Cl^(-), Br^(-), I^(-), NH_(2)^(-) , RNH^(-), R_(2)N^(-), OR^(-), RCOO^(-), R_(3)C^(-), CH_(3)COCH_(2)^(-), OH^(-), CN^(-), N_(3)^(-), SH^(-), HSO_(3)^(-) etc. are charged nucleophiles

In the compound, O_(2)N-C_(6)H_(4)-N=N-C_(6)H_(4)-N(CH_(3))_(2) , the chromophore is

IUPAC name of (C_(2)H_(5))_(3)C-NH_(2) is

IUPAC name of (C_(2)H_(5))_(3)C-NH_(2) is

C_(2)H_(5)Br + NaOH rarr C_(2)H_(5)OH + NaBr , the above reaction is

How are (a) C_(6)H_(5)COOH (b) C_(6)H_(5)OH and (c ) C_(6)H_(5)Cl converted to aniline?

C_(6)H_(6)+CH_(3)Cl to C_(6) H_(5) CH_(3) +HCl The above reaction is an example of

Complete the following reactions: (i) C_(6)H_(5)NH_(2) + CHCl_(3) + alc.KOH to (ii) C_(6)H_(5)N_(2)Cl + H_(3)PO_(2) + H_(2)O to (iii) C_(6)H_(5)NH_(2) + H_(2)SO_(4) ("conc") to (iv) C_(6)H_(5)N_(2)Cl + C_(2)H_(5)OH to (v) C_(6)H_(5)NH_(2) + Br_(2)(aq) to (vi) C_(6)H_(5).NH_(2) +(CH_(3)CO)_(2)O to (vii) C_(6)H_(5)N_(2)Cl overset((i)HBF_(4))underset((ii)NaNO_(2)//Cu.Delta) to

Arrange the following in the decreasing order of basic strength: (a) C_(2)H_(5)NH_(2), C_(6)H_(5)NHCH_(3), (C_(2)H_(5))_(2)NH and C_(6)H_(5)NH_(2) (b) C_(2)H_(5)NH_(2), (C_(2)H_(5))_(2) NH and (C_(2)H_(5))_(3)N (c ) (C_(2)H_(5))_(2)NH, C_(6)H_(5)NH_(2), C_(2)H_(5)NH_(2) and NH_(3)

AAKASH SERIES-GENERAL ORGANIC CHEMISTRY-Subjective Exercise -8
  1. Nucleophiles are either negatively charged or neutral

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  2. Cl^(-), Br^(-), I^(-), NH(2)^(-) , RNH^(-), R(2)N^(-), OR^(-), RCOO^(-...

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  3. overset(..)(N)H(3), R overset(..)(N)H(2), R(2)NH, R(3) overset(..)(N),...

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  4. Electrophiles are electron deficient and attack the substrate where th...

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  5. Electrophiles are either positively charged or neutral

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  6. H^(+). Cl^(+), Br^(+), I^(+), NO(2)^(+), R(3)C^(+), NH(4)^(+), NO^(+),...

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  7. SO(3), BF(3), AlCl(3), FeCl(3), ZnCl(2), BeCl(2) etc., are neutral ele...

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  8. Nucleophiles act as Lewis bases and electrophiles act as Lewis acids

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  9. Ambiphiles are those species which behave like electrophiles and nucle...

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  10. In substitution reactions, an atom or a group attached to a carbon ato...

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  11. Substitution reactions are further classified as free radical, electro...

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  12. Alkanes undergo free radical substitution, aromatic compounds undergo ...

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  13. If the attaching reagent adds on to the substrate molecule without eli...

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  14. In addition reactions, a triple bond is converted to double bond and a...

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  15. Addition reactions are also of three types: Electrophilic, nucleophili...

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  16. Unsaturated hydrocarbons undergo electrophilic addition and carbonyl c...

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  17. In elimination reactions, generally atoms or groups from adjacent carb...

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  18. In elimination reactions, two sigma bonds are lost are a new pi bond i...

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  19. In the preparation of alkenes, dehydration of alcohols, dehydrohalogen...

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  20. In a molecular rearrangement reaction, the product formed is different...

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