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Ambiphiles are those species which behav...

Ambiphiles are those species which behave like electrophiles and nucleophiles. Eg `H- underset(..)overset(..)(O)- H, R - underset(..)overset(..)(O)-H` etc

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Correct the given structure H= overset(H ) overset(|) C- underset(* *) overset( : O : ) overset(|) C-overset(* *)O-H

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underset(OH^(-))overset(KMnO_(4))rarr A underset(H_(2)SO_(4))overset(Dil)rarr B

overset(..)(N)H_(3), R overset(..)(N)H_(2), R_(2)NH, R_(3) overset(..)(N), H_(2)overset(..)(O):, R underset(..)overset(..)(O) R, H_(2) overset(..)S:, R underset(..)overset(..)(S )H, R underset(..)overset(..)S R , etc., are neutral nucleophils

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Mark out the correct order of dipole moment for the following compounds : underset((I))(H- overset(O ) overset(|| ) C-H) underset((II))( H_3C - overset(O) overset(||) C-H) underset((III))( H_3 C - overset(O ) overset(|| ) C- CH_3)

AAKASH SERIES-GENERAL ORGANIC CHEMISTRY-Subjective Exercise -8
  1. Nucleophiles are either negatively charged or neutral

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  2. Cl^(-), Br^(-), I^(-), NH(2)^(-) , RNH^(-), R(2)N^(-), OR^(-), RCOO^(-...

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  3. overset(..)(N)H(3), R overset(..)(N)H(2), R(2)NH, R(3) overset(..)(N),...

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  4. Electrophiles are electron deficient and attack the substrate where th...

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  5. Electrophiles are either positively charged or neutral

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  6. H^(+). Cl^(+), Br^(+), I^(+), NO(2)^(+), R(3)C^(+), NH(4)^(+), NO^(+),...

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  7. SO(3), BF(3), AlCl(3), FeCl(3), ZnCl(2), BeCl(2) etc., are neutral ele...

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  8. Nucleophiles act as Lewis bases and electrophiles act as Lewis acids

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  9. Ambiphiles are those species which behave like electrophiles and nucle...

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  10. In substitution reactions, an atom or a group attached to a carbon ato...

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  11. Substitution reactions are further classified as free radical, electro...

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  12. Alkanes undergo free radical substitution, aromatic compounds undergo ...

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  13. If the attaching reagent adds on to the substrate molecule without eli...

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  14. In addition reactions, a triple bond is converted to double bond and a...

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  15. Addition reactions are also of three types: Electrophilic, nucleophili...

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  16. Unsaturated hydrocarbons undergo electrophilic addition and carbonyl c...

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  17. In elimination reactions, generally atoms or groups from adjacent carb...

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  18. In elimination reactions, two sigma bonds are lost are a new pi bond i...

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  19. In the preparation of alkenes, dehydration of alcohols, dehydrohalogen...

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  20. In a molecular rearrangement reaction, the product formed is different...

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