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The chemical bond fonned due to electron...

The chemical bond fonned due to electron trdllsfer is called ionic bond or electro valcnt bond, Ionic bond will be formed more easily between the elements with low ionization potential and high electron affinity. Energy changes involved during the fonnatioo of ionic compound can be calculated by Born-Haber cycle. Lattic enthalpy changes are directly proportional to the stability of ionic compound
Boron-Haber cycle is based on

A

Faraday's law

B

Gay-Lumar's law

C

Emeton's law

D

Hess's law

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The correct Answer is:
D
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The chemical bond fonned due to electron trdllsfer is called ionic bond or electro valcnt bond, Ionic bond will be formed more easily between the elements with low ionization potential and high electron affinity. Energy changes involved during the fonnatioo of ionic compound can be calculated by Born-Haber cycle. Lattic enthalpy changes are directly proportional to the stability of ionic compound Most stable ionic compound among the following is

The Chemical bond fonned due to electron transfer is called ionic bond or electro valent bond Ionic bond will be formed more easily between the elements with low ionisation potential and high electron affinity. Energy changes involved during the fonnation of ionic compound can be calculated by Born - Haber cycle. Lattice enthalpy changes are directly proportional to the stability of ionic compound. Which or the following has electrovalent bond ?

Ionic bond is defined as the electrostatic force of attraction holding the oppositely charged ions. Ionic compounds are mostly crystalline solids having high melting and boiling points, electrical conductivity in molten state, solubility in water etc., Covalent bond is defined as the force which binds atoms of same or different elements by mutual sharing of electrons in a covalent bond. Covalent compounds are solids, liquids or gases. They are low melting and boiling point compounds. They are more soluble in non polar solvents. The amount of energy released when one mole of ionic solid fonned by close packing of gaseous ions is called

Ionic bond is defined as the electrostatic force of attraction holding the oppositely charged ions. Ionic compounds are mostly crystalline solids having high melting and boiling points, electrical conductivity in molten state, solubility in water etc., Covalent bond is defined as the force which binds atoms of same or different elements by mutual sharing of electrons in a covalent bond. Covalent compounds are solids, liquids or gases. They are low melting and boiling point compounds. They are more soluble in non polar solvents. The valence electrons not involved in fonnation of covalent bonds are called

Ionic bond is defined as the electrostatic force of attraction holding the oppositely charged ions. Ionic compounds are mostly crystalline solids having high melting and boiling points, electrical conductivity in molten state, solubility in water etc., Covalent bond is defined as the force which binds atoms of same or different elements by mutual sharing of electrons in a covalent bond. Covalent compounds are solids, liquids or gases. They are low melting and boiling point compounds. They are more soluble in non polar solvents. Examples of covalent compounds are

Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic character is due to shifting of the electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic character is described as polar covalent bond. Polar covalent molecules can exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of molecules depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moments help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis-and traps-isomers, ortho-, meta-and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula : % " ionic character " = ("Experimental value of dipole moment ")/("Theoretical value of dipole moment ") xx 100 Which are non-polar molecules?

Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic character is due to shifting of the electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic character is described as polar covalent bond. Polar covalent molecules can exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of molecules depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moments help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis-and traps-isomers, ortho-, meta-and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula : % " ionic character " = ("Experimental value of dipole moment ")/("Theoretical value of dipole moment ") xx 100 The dipole moment of NF_(3) is very much less than that of NH_(3) because :

Hydrogen bonding is said to be formed, -when sightly acidic hydrogen-atom attached to a strongly, electronegative fluorine, oxygen or nitrogen atom. is held with weak. electrostatic forces by the non-bonded pair of electrons of another atom. The co-ordination number of hydrogen in such cases is two. It acts as a bridge between two atoms, to one of which it is covalently bonded and to other attached through electrostatic forces, also called hydrogen bond. Though the hydrogen atoms in a methyl group are not polarised, if an electronegative group like chloro, carbonyl, nitro or cyano (in order to increase electronegativity) is attached to it, the C-H bond gets polarised due to the inductive effect and the hydrogen atom becomes slightly acidic resulting in the formation of weak hydrogen bonds. Though a weak bond the H-bond effects is large number of the physical properties of compounds some of which are - Boiling points of liquids - Solubility of polar compounds in polar solvents (containig H attached with strong electronegative atom) - Viscosity of liquids . Acidity Which of the following combinations can involve hydrogen bonding I) Mixture of KF and HF " " II) Mixture of CH_(3)COCH_(3) and CHCI_(3) III) Mixture of NH_(4) CI and H_(2)O" " IV) Mixture of CH_(3) and H_(2)O