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Covalent molecules formed by heteroatoms...

Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic character is due to shifting of the electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic character is described as polar covalent bond. Polar covalent molecules can exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to `10^(-18)` esu cm.
Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of molecules depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moments help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis-and traps-isomers, ortho-, meta-and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula :
`% " ionic character " = ("Experimental value of dipole moment ")/("Theoretical value of dipole moment ") xx 100`
Which are non-polar molecules?

A

`XeF_(4)`

B

`BF_(3)`

C

`NH_(3)`

D

`H_(2)O`

Text Solution

Verified by Experts

The correct Answer is:
D
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Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic character is due to shifting of the electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic character is described as polar covalent bond. Polar covalent molecules can exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of molecules depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moments help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis-and traps-isomers, ortho-, meta-and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula : % " ionic character " = ("Experimental value of dipole moment ")/("Theoretical value of dipole moment ") xx 100 A diatomic molecule has a dipole moment of 1.2 D. If the bond length is 1.0 xx 10^(-8) cm, what fraction of charge does exist on each atom?

Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic character is due to shifting of the electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic character is described as polar covalent bond. Polar covalent molecules can exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of molecules depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moments help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis-and traps-isomers, ortho-, meta-and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula : % " ionic character " = ("Experimental value of dipole moment ")/("Theoretical value of dipole moment ") xx 100 Arrange the following compounds in increasing order of dipole moments, toluene (I), o- dichlorobenzene (II), m-dicblorobenzene (III) and p dichlorobenzene (IV) :

Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic character is due to shifting of the electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic character is described as polar covalent bond. Polar covalent molecules can exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of molecules depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moments help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis-and traps-isomers, ortho-, meta-and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula : % " ionic character " = ("Experimental value of dipole moment ")/("Theoretical value of dipole moment ") xx 100 The dipole moment of NF_(3) is very much less than that of NH_(3) because :

How is percentage of ionic character of covalent substance calculated?

Which possesses highest percentage of ionic character

Molecule with zero dipole moment is

Dipole moment is least in the molecule

The molecule having zero dipole moment is

The compound which has polar covalent bond is