Home
Class 12
CHEMISTRY
For M^(2+)//M and M^(3+)//M^(2+) systems...

For `M^(2+)//M and M^(3+)//M^(2+)` systems the `E^(@)` values for some metals are as follows:
`{:(Cr^(2+)//Cr,-0.9V,Cr^(3)//Cr^(2+),-0.4V),(Mn^(2+)//Mn,-1.2V,Mn^(3+)//Mn^(2+),+1.5V),(Fe^(2+)//Fe,-0.4V,Fe^(3+)//Fe^(2+),+0.8V):}`
Use this data to comment upon: (i) the stability of `Fe^(3+)` in acid solution as compared to that of `Cr^(3+)` or `Mn^(3+)` and
(ii) the ease with which iron can be oxidised as compared to a similar process for either chrmoium or magnganess metal.

Text Solution

Verified by Experts

(i) The `M^(3+)|M^(2+)` values suggest that `Fe^(3+)` ions in acidic medium is more stable than `Mn^(3+)` ions and less stable than `Cr^(3+)` because of higher reduction potential.
(ii) `M^(2+)|M` is most negative for Mn and hence Mn will be most easily oxidized. The ease wiht which oxidation occurs will be `Mn gt Cr gt Fe`
Promotional Banner

Topper's Solved these Questions

  • THE D-AND F-BLOCK ELMENTS

    KUMAR PRAKASHAN|Exercise Section D (Multiple Choice Questions)|21 Videos
  • THE D-AND F-BLOCK ELMENTS

    KUMAR PRAKASHAN|Exercise Section D (Multiple Choice Questions More than one options)|10 Videos
  • THE D-AND F-BLOCK ELMENTS

    KUMAR PRAKASHAN|Exercise Section B (Intext Questions and Answers)|10 Videos
  • SURFACE CHEMISTRY

    KUMAR PRAKASHAN|Exercise SECTION - E (MCQs asked in GUJCET/Board Exams)|52 Videos
  • THE P-BLOCK ELEMENTS

    KUMAR PRAKASHAN|Exercise SECTION-E (MULTIPLE CHOICE QUESTIONS (MCQS)) (MCQS ASKED IN BOARD EXAM)|77 Videos

Similar Questions

Explore conceptually related problems

What are the fractions of Fe^(2+) and Fe^(3+) in Fe_(0.93) O respectively ?

KUMAR PRAKASHAN-THE D-AND F-BLOCK ELMENTS-Section C (Textual Exercise)
  1. Describe the oxidising action of potassium dichromate and write the io...

    Text Solution

    |

  2. Describe the preparation of potassium permanganate. How doe the acidif...

    Text Solution

    |

  3. For M^(2+)//M and M^(3+)//M^(2+) systems the E^(@) values for some me...

    Text Solution

    |

  4. Predict which of the following will be coloured in aqueous solution? T...

    Text Solution

    |

  5. Compare the stability of (+2) oxidation state for the elements of the ...

    Text Solution

    |

  6. Compare the chemistry of actinoids with that of the lanthanoids with s...

    Text Solution

    |

  7. How would you account for the following: (i) Of the d^(4) species, C...

    Text Solution

    |

  8. What is meant by 'disproportionation? Give two examples of disproporti...

    Text Solution

    |

  9. Which metal in the first series of transition metals exhibits (+1) oxi...

    Text Solution

    |

  10. Calculate the number of unpaired electrons in the following gasesous i...

    Text Solution

    |

  11. Give examples and suggest reasons for the following features of the tr...

    Text Solution

    |

  12. Indicate the steps in the preparation of: (i) K(2)Cr(2)O(7) from chr...

    Text Solution

    |

  13. What are alloys? Name an important alloy which contains some of the la...

    Text Solution

    |

  14. What are inner transition elements ? Decide which of the following ato...

    Text Solution

    |

  15. The chemistry of the actinoid elements is not so smooth as that of the...

    Text Solution

    |

  16. Which is the last element in the series of the actinoids ? Write the e...

    Text Solution

    |

  17. Use Hund's rule to derive the electronic configuration of Ce^(3+) ion,...

    Text Solution

    |

  18. Name the members of the lanthanoid series which exhibit (+4) oxidation...

    Text Solution

    |

  19. Write the electronic configuration of the elements with the atomic num...

    Text Solution

    |

  20. Compare the general characteristics of the first series of the transit...

    Text Solution

    |