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Amygdalin, a compound isolated from the ...

Amygdalin, a compound isolated from the pits of apricots, peaches and wild cherries. Although it has no known therapeutic value, it has been used as unsanctioned anticancer drug. One hydrolysis product formed from Amygdalin is mandelic acid used in common skin problems.

If `[alpha]` of solution of mandelic acid is + 50.56 , the ee% will be

A

enantiomeric excess of solution is 50%

B

enantiomeric excess of solution is 60%

C

enantiomeric excess of solution is 32%

D

enantiomeric excess of solution is 80%

Text Solution

Verified by Experts

The correct Answer is:
C

enantiomeric excess of solution is 32%
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Amygdalin, a compound isolated from the pits of apricots, peaches and wild cherries. Although it has no known therapeutic value, it has been used as unsanctioned anticancer drug. One hydrolysis product formed from Amygdalin is mandelic acid used in common skin problems. Number of stereogenic centers present in (A)

Amygdalin, a compound isolated from the pits of apricots, peaches and wild cherries. Although it has no known therapeutic value, it has been used as unsanctioned anticancer drug. One hydrolysis product formed from Amygdalin is mandelic acid used in common skin problems. Pure (R)-mandelic acid has specific rotation of -154 and sample contains 60% of (R) isomer and 40 % of its enantiomer. [alpha] of mixture is