Home
Class 12
CHEMISTRY
4HBr+O(2)to2H(2)O+2Br(2). The moleculari...

`4HBr+O_(2)to2H_(2)O+2Br_(2)`. The molecularity of the reaction appears as 5, but experimentally, it is 2.
Explain.

Text Solution

Verified by Experts

The mechanism of oxidation reaction of HBr is given in three steps.
`HBr+O_(2) to HOOBr, HOOBr+HBr to 2HOBr HOBr+HBr to H_(2)O+Br_(2)`
Molecularity of each step is `2`.
The overall molecularity of the slowest step `(1st)` is `2`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    AAKASH SERIES|Exercise Subjective Exercise-I(Long answer question)|1 Videos
  • CHEMICAL KINETICS

    AAKASH SERIES|Exercise Subjective Exercise-I(Short answer question)|4 Videos
  • CHEMICAL KINETICS

    AAKASH SERIES|Exercise PRACTICE EXERCISE|55 Videos
  • CHEMICAL KINETCS

    AAKASH SERIES|Exercise EXERCISE - 3.2|45 Videos
  • CHEMICAL THERMODYNAMICS

    AAKASH SERIES|Exercise Additional Practice Exercise|54 Videos

Similar Questions

Explore conceptually related problems

2H_(2) O_(2) to 2 H_(2)O_ + O_(2) . This reaction is

x Br_(2) + y KOH rarr KBr + KBrO_(3) + H_(2)O here the equivalent mass of Br_(2) of the reaction is how many times the equivalent mass of Br_(2) as reductant.

MnO_(2)+4HClrarrMnCl_(2)+Cl_(2)+2H_(2)O , In the reaction MnO_(2) acts as

PbS+4H_(2)O_(2)toPbSO_(4)+4H_(2)O . The reaction of H_(2)O_(2) with is an example of . .. . reaction.

H_2O_2 + H_2O to H_2O^(+) toHO_2^- This reaction indicates

Explain the reaction of heavy water with Na, Na_2O, N_2O_5 and Al_4C_3

For the reaction, KO_(2) + H_(2)O+CO_(2) rarrKHCO_(3) +O_2 the mechanism of reaction suggests that:

AAKASH SERIES-CHEMICAL KINETICS-Example
  1. At 25^(@)C the activation energy for a catalysed reaction is 126 KJ ...

    Text Solution

    |

  2. Rate of a chemical reaction depends on concentration of reactant is...

    Text Solution

    |

  3. For a reaction a, A to Products , the units of rate constant are ...

    Text Solution

    |

  4. Units of rate constnat is the same for the elementary reactions : ...

    Text Solution

    |

  5. Rate expression for two reaction are : (a) "rate"(a) = k(a)[A] and (b...

    Text Solution

    |

  6. The decomposition of nitrogen pentoxide is given as 2N(2)O(5) to 4...

    Text Solution

    |

  7. The experimental data for the reaction 2A+B(2)to2AB is given below. Ba...

    Text Solution

    |

  8. 4HBr+O(2)to2H(2)O+2Br(2). The molecularity of the reaction appears as ...

    Text Solution

    |

  9. 75%. of a first order reaction is complete is 30 min. Calculate (a) ha...

    Text Solution

    |

  10. A first order reaction is 20% complete in 10 min. How long it takes...

    Text Solution

    |

  11. The rate constant of a reaction is 2.5xx10^(-2)" L mol"^(-1)s^(-1). Ca...

    Text Solution

    |

  12. At 193^(@)C , the rate law for the reaction 2Cl(2)O to 2Cl(2) + O(2)...

    Text Solution

    |

  13. The initial concentration of ethyl acetane is 0.85 mol L^(-1) . Fo...

    Text Solution

    |

  14. 2NO + H(2) to N(2)O + H(2)O , The reaction , follows third order kine...

    Text Solution

    |

  15. The rate of a reaction is given as , rate = k[X]^(3//2) [Y]^(-1//...

    Text Solution

    |

  16. A and B are two radioctive substance with half lives 20 min and d30...

    Text Solution

    |

  17. A reaction is first order in A and second order in B. How the rate is ...

    Text Solution

    |

  18. For the reaction X to Y +Z if the initial concentration of X was ...

    Text Solution

    |

  19. Half-life of ""^(210)Pb is 22 years. 2gram of lead is allowed decay f...

    Text Solution

    |

  20. Radium disintegrates to give radon. Write chemical equation as well as...

    Text Solution

    |