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Hardy - Schulz rules are based on of el...

Hardy - Schulz rules are based on _____ of electrolyte ions coagulating the colloid

A

Size

B

Charge

C

Magnetic nature

D

Molar mass

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The correct Answer is:
B
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Coagultion is the process by which the dispersed phase of a colloid is made to aggregate and thereby separate from the continuous phase. The minimum concentration of an electrolyte in milli-moles per litre of the electrolyte solution which is required to cause the coagulation of colloidal sol is called coagulation value. Therefore higher is the coagulating power of effective ion, smaller will be the coagulation value. Coagulation value of the electrolyte alpha 1/("coagulating power") The coagualtion value of different electrolytes are different. This behaviour can be easily understood by hardy-schulze rule which states. "The greater is the valency of the effective ion greater is its precipitating power." The coagulation of colloidal particles of the sol can be caused by :

Coagultion is the process by which the dispersed phase of a colloid is made to aggregate and thereby separate from the continuous phase. The minimum concentration of an electrolyte in milli-moles per litre of the electrolyte solution which is required to cause the coagulation of colloidal sol is called coagulation value. Therefore higher is the coagulating power of effective ion, smaller will be the coagulation value. Coagulation value of the electrolyte alpha 1/("coagulating power") The coagualtion value of different electrolytes are different. This behaviour can be easily understood by hardy-schulze rule which states. "The greater is the valency of the effective ion greater is its precipitating power." As_2S_3 sol is negatively charged, capacity to precipitate it is highest in which ion ?

A solution which remains in equilibrium with undissolved solute is said to be saturated. The concentration of a saturated solution at a given temperature is called solubility. The product of concentration of ions in a saturated solution of an electrolyte at a given temperature, is called solubility product (K_(sp)) . For the electrolyte, A_(x),B_(y),:A_(x),B_(y(s)) rarr xA^(y+)+ y^(Bx-) , with solubility S, the solubility product (K_(sp)) =x^(x)xxy^(y) xx s^(x+y) . While calculating the solubility of a sparingly soluble salt in the presence of some strong electrolyte containing a common ion, the common ion concentration is practically equal to that of strong electrolyte. If in a solution, the ionic product of an clectrolyte exceeds its K_(sp) , value at a particular temperature, then precipitation occurs. The solubility of BaSO_(4) , in 0.1 M BaCl_(2) , solution is (K_(sp) , of BaSO_(4), = 1.5 xx 10^(-9))

A solution which remains in equilibrium with undissolved solute is said to be saturated. The concentration of a saturated solution at a given temperature is called solubility. The product of concentration of ions in a saturated solution of an electrolyte at a given temperature, is called solubility product (K_(sp)) . For the electrolyte, A_(x),B_(y),:A_(x),B_(y(s)) rarr xA^(y+)+ y^(Bx-) , with solubility S, the solubility product (K_(sp)) =x^(x)xxy^(y) xx s^(x+y) . While calculating the solubility of a sparingly soluble salt in the presence of some strong electrolyte containing a common ion, the common ion concentration is practically equal to that of strong electrolyte. If in a solution, the ionic product of an clectrolyte exceeds its K_(sp) , value at a particular temperature, then precipitation occurs. The solubility of PbSO_(4) , in water is 0.303 g/l at 25^(@) C, its solubility product at that temperature is

(A) : Addition of CH_(3)COOH and HCOOH electrolytes causes coagulation by neutralising the charge of the colloid (latex) (R) : Rubber particles are negatively charged

{:("Column - I", "Column - II"),("A)Coagulation ","p) Scatering of light"),("B) Peptization", "q) Purification of colloidal solution"),("C) Tyndall effect","r) Addition of electrolyte"),("D) Dialysis","s) Precipitation of colloidal solution"):}

The coagulation values in millimoles per litre of the electrolytes used for the coagulation of As_(2)S_(3) are given : I. (NaCl) = 52 II. (BaCl_(2)) = 0.69 " " III. (MgSO_(4)) = 0.22 Correct order of their coagulating power is

A detergent [C_12 H_2SO_(4)^(-) Na^(+)] solution becomes a colloidal sol at a conc. of 10^(-3)M on an average 10^13 colloidal particles are present in lmm what is the average no.of ions are contain in one colloidal particle (micelle) no.of ions 6 x 10^x . x is .......

AAKASH SERIES-SURFACE CHEMISTRY-Objective Excersice - 2
  1. As the size of gold particle increases the colour of solution varies a...

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  2. Which one of the following forms a negativity charged sol?

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  3. The order of coagulating power of PO(4)^(3-), SO(4)^(2-) and Cl^(-) in...

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  4. Which of the following is correct about lyophillic sol ?

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  5. Peptization denots

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  6. The migration of colloidal solute particles in a colloidal solution, w...

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  7. Blue colour of the sky is due to

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  8. The order of coagulating power of PO(4)^(3-), SO(4)^(2-) and Cl^(-) in...

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  9. On adding AgNO(3) solution to KI solution, a negatively charged colloi...

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  10. On addiction of 1ml solution of 10% NaCl to 10ml gold sol in the prese...

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  11. Hardy - Schulz rules are based on of electrolyte ions coagulating the...

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  12. Which of the following is a kinetic property of sols ?

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  13. Brownian movement is mainly is due to

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  14. Which of the following is a non electrolytic colloidal sol

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  15. Sodium stearate forms associated colloids

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  16. Gold number of a lyophilic solution is such property that

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  17. Ferric chloride on rubbing to a bleeding wound causes

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  18. An example of a positively of a positively charged sol is

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  19. When the purc solvent diffuses out of the solution through the semi-pe...

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  20. If the gold number of potato starch is 25, how many grams of it is req...

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