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Aliphatic amines are more basic than aro...

Aliphatic amines are more basic than aromatic amines. Explain

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Explain the following: a) why the boiling points of primary amines are higher than those of the corresponding tertiary amines of similar molar mass. b) why aromatic amines are lesser basic than aliphatic amines ? c) why alcohols are more acidic than amines of comparable molar mass? d) Gabriel phthalimide synthesis is not useful in the preparation of aromatic primary amines?

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AAKASH SERIES-NITROGEN CONTAINING COMPOUNDS-Exercise 5.2
  1. Write resonance structures to explain the nitration of nitrobenzene gi...

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  2. Why amines are basic. Explain

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  3. Aliphatic amines are more basic than aromatic amines. Explain

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  4. Write the effect of substituents on the basic nature of aniline

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  5. Write the mechanism of Hoffmann bromamide reaction.

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  6. Write the behaviour of aliphatic 1^(@), 2^(@) and 3^(@) amines towards...

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  7. How the three types of amines are distinguished?

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  8. Write the reactions of aliphatic and aromatic primary amines with nitr...

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  9. Aniline is insoluble in water, but ethyl amine is soluble. Explain

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  10. Aniline is less basic than ammonia. Why?

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  11. How is chlorobenzene prepared from aniline?

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  12. What is Hinsberg's reagent? How it is useful to identiy 1^(@), 2^(@), ...

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  13. Write resonance structures of benzee diazonium ion

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  14. Diazonium salts are useful for preparation of halobenzenes. Give react...

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  15. Aromatic amines can not be prepared by Gabriel phthalimide method. Jus...

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  16. Comment on the conversion of methyl chloride into acetaldehyde

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  17. How ethyl cyanide is converted to diethyl ketone? What are the special...

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  18. X overset(Sn, HCl)rarr Y overset(KNO(2), HCl)rarr Z. The compound 'Z' ...

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  19. How is aniline converted to benzene? Discuss the reactions

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  20. C(6)H(5)N(2)Cl underset(KCN)overset(CuCN)rarr A underset(H^(+))overset...

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