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Fe^(3+) can oxidise halide ions. Discuss...

`Fe^(3+)` can oxidise halide ions. Discuss. 

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A quantity of 25.0 mL of solution containing both Fe^(2+) and Fe^(3+) ions is titrated with 25.0 mL of 0.0200 M KMnO_(4) (in dilute H_(2)SO_(4) ). As a result, all of the Fe^(2+) ions are oxidised to Fe^(3+) ions. Next 25 mL of the original solution is treated with Zn metal finally, the solution requires 40.0 mL of the same KMnO_(4) solution for oxidation to Fe^(3+) . MnO_(4)^(-)+5Fe^(2+)+8H^(+)toMn^(2+)+5Fe^(3+)+4H_(2)O IF 0.02 M K_(2)Cr_(2)O_(7) is used instead of 0.02 M KMnO_(4) its volume required in these titrations are respectively

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AAKASH SERIES-ELEMENTS OF D - BLOCK-EXERCISE - 5.2
  1. Ferrous oxalate is used in developing black and white photographic fil...

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  2. In 3d-series which element has positive E(M^(2+)//M)^(@) value? Why?

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  3. Fe^(3+) can oxidise halide ions. Discuss.

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  4. Why calculated magnetic moment of Co^(2+) is less than the experimenta...

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  5. Mn^(x+) has a magnetic moment of 4.9 BM. Calculate the value of x in t...

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  6. A salt of 3d metal gave a white precipitate with NH(4)OH, but dissolve...

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  7. What is the percentage of number of ferro ions in the non-stoichiometr...

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  8. Addition of appreciable amount KMnO(4) in conc. H(2)SO(4) explodes. Ex...

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  9. An aqueous solution of Al(2)(SO(4))(3),FeSO(4) and chrome alum is heat...

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  10. E^(@) for Mn^(3+), Mn^(2+) is more positive than that for Fe^(3+), Fe^...

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  11. Amongest the bivalent ions of 3d-elements, Mn(II) shows maximum parama...

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  12. Copper is regarded as transition metal, though it has completely fille...

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  13. Compounds of iron are coloured and paramagnetic. Explain.

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  14. In 3d-series which element cannot displace hydrogen gas from dilute ac...

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  15. Mn^(3+) is less stable than Mn^(2+) and Mn^(4+) ions. Why?

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  16. Acidified dichromate solution turns green when sodium sulphide is adde...

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  17. How lanthanides differ from actinides in their oxidation states?

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  18. Is any actinide has no electrons in 5f-subshell? If so name it.

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  19. What is actinoid contraction ?

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  20. Only chelate complexes of lanthanides are known, other complexes are l...

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