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Only chelate complexes of lanthanides ar...

Only chelate complexes of lanthanides are known, other complexes are less stable. Substainliate. 

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Among the following the chelate complexes are

On the basis of stability of complex extity in the solution, complexes may be of two types, perfect, imperfect complexes, the stabilies depends upon the extent of dissociation which in turn depends on the strength of M-L band. The dissociation of complex may be expressed [ML_(x)P^(+)hArrMy^(+)+xL and eq. constant of this dissociation equilibrium is called instability constant. The stability of complex depends are EAN, charge on central atom, basic nature chelation, nature of metal ion and ligand acc. to HSAB principle Which complex in most stable ?

On the basis of stability of complex extity in the solution, complexes may be of two types, perfect, imperfect complexes, the stabilies depends upon the extent of dissociation which in turn depends on the strength of M-L band. The dissociation of complex may be expressed [ML_(x)P^(+)hArrMy^(+)+xL and eq. constant of this dissociation equilibrium is called instability constant. The stability of complex depends are EAN, charge on central atom, basic nature chelation, nature of metal ion and ligand acc. to HSAB principle The EAN of Co in Co(CO)_(4) is 35. Hence it is less stable. It attains stability by

On the basis of stability of complex extity in the solution, complexes may be of two types, perfect, imperfect complexes, the stabilies depends upon the extent of dissociation which in turn depends on the strength of M-L band. The dissociation of complex may be expressed [ML_(x)P^(+)hArrMy^(+)+xL and eq. constant of this dissociation equilibrium is called instability constant. The stability of complex depends are EAN, charge on central atom, basic nature chelation, nature of metal ion and ligand acc. to HSAB principle Which of the following does not follow EAN rule?

Which of the following complexes is a chelate ?

(A): Chelates are relatively more stable than non-chelated complexes. (R): Complexes containing ligands which can be easily replaced by other ligands are called labile complexes.

The f-block consists of the two series lanthanoids and actinoids. Because Lanthanum closely resembles the Lanthanoids. The Lanthanoid resemble one another more closely than do the members ofordinary transition elements in any series. They have only one stable oxidation state. The chemistry of the actinoids is on the other hand, much more complicated. The complication arises partly owing to the occurance ofa wide range of oxidation states in these elements and partly because their radioactivity creates special problems in their study Wrong statement of the following is

Actinides have higher tendency to form complexes than Lanthanides, due to

Read the following statements about WBCs and select the correct option 1) Lymphocytes are responsible for immune responses of the body 2) Basophils are least in number among white blood cells. 3) Eosinophils can engulf antigen-antibody complexes 4) Monocytes are the only phagocytic ceils of blood so that they are waited internal scavengers.

AAKASH SERIES-ELEMENTS OF D - BLOCK-EXERCISE - 5.2
  1. Mn^(x+) has a magnetic moment of 4.9 BM. Calculate the value of x in t...

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  2. A salt of 3d metal gave a white precipitate with NH(4)OH, but dissolve...

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  3. What is the percentage of number of ferro ions in the non-stoichiometr...

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  4. Addition of appreciable amount KMnO(4) in conc. H(2)SO(4) explodes. Ex...

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  5. An aqueous solution of Al(2)(SO(4))(3),FeSO(4) and chrome alum is heat...

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  6. E^(@) for Mn^(3+), Mn^(2+) is more positive than that for Fe^(3+), Fe^...

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  7. Amongest the bivalent ions of 3d-elements, Mn(II) shows maximum parama...

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  8. Copper is regarded as transition metal, though it has completely fille...

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  9. Compounds of iron are coloured and paramagnetic. Explain.

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  10. In 3d-series which element cannot displace hydrogen gas from dilute ac...

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  11. Mn^(3+) is less stable than Mn^(2+) and Mn^(4+) ions. Why?

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  12. Acidified dichromate solution turns green when sodium sulphide is adde...

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  13. How lanthanides differ from actinides in their oxidation states?

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  14. Is any actinide has no electrons in 5f-subshell? If so name it.

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  15. What is actinoid contraction ?

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  16. Only chelate complexes of lanthanides are known, other complexes are l...

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  17. Basic nature of Lu(OH)(2) is less than that of La(OH)(3). Why?

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  18. Which lanthanide is synthetic? Write its electronic configuration.

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  19. Trivalent ions of Eu (Z = 63) and Tb (Z = 65) have same colours. Expla...

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  20. Eu^(2+) is good reductant, but Ce^(4+) is good oxidant. Explain.

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