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Give the IUPAC names of the compounds. C...

Give the IUPAC names of the compounds. Classify them as alkyl, allylic, benzylic, vinylic and aryl halides and also as primary, secondary and tertiary halides.
` (i ) (CH_3)_3 C CH_2 CH (Cl) CH_3`
`(ii ) CH_3 CH_2 CH=CHCH_2 Cl,`
`(iii ) (CH_3)_2 CHCH_2 CH=C (Cl) CH_2 CH_3 and `
`(iv ) C_6 H_5 C (Cl ) CH_3)_2`

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Verified by Experts

`(i) underset("2- chloro-4,4- dimethylpentane alkyl halide ( secondary)") ( H_3 overset(5)(C ) - underset(CH_3) underset(| ) overset( CH_3) overset(4|) (C ) - overset(3 )(CH_2) - underset(Cl ) underset(| ) overset(2)(CH) - overset(1) (CH_3))`
`(ii ) underset("1-Chloropent-2-ene Allylic halide ( primary )") ( overset(5) (CH_3) overset(4)(CH_2) overset(3) (CH)= overset(2) (CH)overset(1)(CH_2) Cl)`
`(iii ) underset("2-chloro-2-phenylpropane henzylic halide ( tertiary)") ( C_6 H_5 - underset(CH_3) underset(| ) overset(Cl)overset(|)(C ) - CH_3)`
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AAKASH SERIES-ALKYL AND ARYL HALIDES-OBJECTIVE EXERCISE - 4 (ASSERTION (A) & REASON (R) TYPE QUESTIONS)
  1. Give the IUPAC names of the compounds. Classify them as alkyl, allylic...

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  2. (A) Towards SN2 reaction, order of reactivity is CH3Br > CH3CH2Br > (C...

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  3. (A) Pure chloroform does not give precipitate with AgNO3 solution. (...

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  4. (A) Addition of bromine to 2-butene yields 2,3-dibromobutane. (R) Br...

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  5. (A) Thionyl chloride reacts with primary alcohols to form pure alkyl h...

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  6. (A) The boiling points of alkyl halides decrease in the order RI > RBr...

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  7. (A) KCN reacts with methyl chloride to give methyl cyanide and methyl ...

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  8. (A) In monohaloarenes, further electrophilic substitution occurs at or...

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  9. (A) Benzonitrile is prepared by the action of chlorobenzene with KCN ...

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  10. (A) Styrene on reaction with HBr gives 1-bromo-1-phenyl ethane. (R) ...

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  11. (A) NBS is a specific reagent for allylic bromination (R) Allylic br...

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  12. (A) Benzyl bromide when kept in acetone - water, produces benzyl alcoh...

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  13. (A) 2-Bromobutane on reaction with sodium ethoxide in ethanol gives 1-...

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  14. (A) Chloral reacts with phenyl chloride to form DDT (R) It is an ele...

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  15. (A) CH3overset(Cl)overset(|)(C)HCH2CH3overset(Alc.KOH)(rarr)CH3CH=CHCH...

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  16. (A) Addition of HBr on but-2-ene gives two structural isomeric product...

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  17. (A) The nature of the solvent can influence the rotation of plane pola...

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  18. (A) SN2 reactions are exothermic (R) SN2 reactions are thermochemica...

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  19. (A) Chloroform can be used as general anaesthetic. (R) In presence o...

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  20. (A) Ethyl chloride gives C2H5CN as major product with alc. KCN but C2H...

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