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Which of the following reactions possess...

Which of the following reactions possess highest `Delta H` value

A

`CH_3Br to CH_3^(+) + Br^(-)`

B

`CH_3CH_2Br to CH_3CH_3^+`

C

`CH_3 - undersetoverset(|)(CH_3)(C )H - Br to CH_3-CH^(+) - CH_3 +Br^-`

D

`(CH_3)_3 C - Br to (CH_3)_3 C^(+) + Br^(-)`

Text Solution

Verified by Experts

The correct Answer is:
A

Energy require by aryl halide that forms stable carbocation (when C-X bond breaks) is less than the aryl halide that forms less stable carbocation `""^(+)CH_3` is stable more `Delta H` is required
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