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Aliphatic nucleophilic substitution main...

Aliphatic nucleophilic substitution mainly takes place by two mechanisms (i.e) `SN^1 & SN^2` Primary halides mainly undergo by `SN^2` mechanism and are favourable in polar aprotic solvents. `SN^1` reactions takes place mainly by tertiary halide and are more favourable in polar protic solvents, In case of tertiary halides, `E_1` comes competition to `SN^1` reaction. Keeping in view of these general points, answer the following questions
`(+)C_6H_5CH(CH_3)Cl to (pm) C_6H_5CH(OH)CH_3` in which of the following solvents, the above reaction is most favourable

A

75% water + 25% `CH_3OH`

B

25% water + 75% methanol

C

100% methanol

D

10% water + 90% methanol

Text Solution

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The correct Answer is:
A

Given reaction follows `SN^1` mechanism, which takes place favorable in polar solvents due to formation of cation is the intermediate step
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Aliphatic nucleophilic substitution mainly takes place by two mechanisms (i.e) SN^1 & SN^2 Primary halides mainly undergo by SN^2 mechanism and are favourable in polar aprotic solvents. SN^1 reactions takes place mainly by tertiary halide and are more favourable in polar protic solvents, In case of tertiary halides, E_1 comes competition to SN^1 reaction. Keeping in view of these general points, answer the following questions Which of the following reactions, the reactions takes place by SN^1 mechanism mainly.

In which of the following solvents, SN^2 is most favourable

Why S_(N^(1)) reactions are favourable in polar solvents?

Which of the following are polar protic solvents

SN^1 reactions never occur on

Which of the following alkyl halides mainly undergo reaction by SN^2 mechanism.

Which of the following compounds do not readily give SN^2 reaction

Which of the following is / are polar aprotic solvents

Which of the following undergo SN reaction at a fastest rate than others

Which of the following statements regarding SN reaction is right