Home
Class 12
CHEMISTRY
In the study of chlorination of propane ...

In the study of chlorination of propane four products (A,B,C and D) (structural isomerism) of the formula `C_3H_6Cl_2` were isolated. Each was further chlorinated to provide trichloro products `(C_3H_5Cl_3)` It was found that A provide one trichloro produce, B gave two and C and D each gave three. It is found that D is optically active.
Correct formula of the product of chlorination of B is

A

`Cl_2 CH CH_2 CH_2 Cl`

B

`Cl CH_2 Cl CH CH_2 Cl`

C

both a and b

D

Text Solution

Verified by Experts

The correct Answer is:
B
`Cl - CH_2 - oversetunderset(|)(Cl)(C )H - CH_2 - Cl`
Promotional Banner

Similar Questions

Explore conceptually related problems

A hydrocarbon P has molecular formula C_8H_(16) , and it does not undergo hydrogenation with raney Ni. A on free radical chlorination yields three monochloro derivatives Q, R and S (all structural isomers) with their molecular formula C_8 H_(15)Cl . Only Q can show optical isomerism R. On further chlorination produces a dichloride C_8 H_(14) Cl_2 , as one of the several isomers which on heating with sodium metal in etheral solution gives bicyclo [2, 2, 2] octane. If S is dichlorinated, how many isomers would be produced? (exclude stereoisomers)

A hydrocarbon P has molecular formula C_8H_(16) , and it does not undergo hydrogenation with raney Ni. A on free radical chlorination yields three monochloro derivatives Q, R and S (all structural isomers) with their molecular formula C_8 H_(15)Cl . Only Q can show optical isomerism R. On further chlorination produces a dichloride C_8 H_(14) Cl_2 , as one of the several isomers which on heating with sodium metal in etheral solution gives bicyclo [2, 2, 2] octane. How many stereoisomers are possible for Q?

An alkane C_7H_(16) is produced by the reaction of lithium di (3-pentyl) cuprate with ethyl bromide. The structural formula of the product is

An organic compound with molecular formula C_5H_5Cl exists in two optically active forms A and B . A on hydrogenation in presence of a catalyst gives an optically inactive compound (C). While B gives an optically active compound D. The structure of A is