Popoffs|rule

Carbonyl compounds give different oxidation products with different reagents. Several oxidising agents can be used to oxides carbonyl compound. Ammonical silver nitrate (Tollens' reagent) oxidises aliphitic as well as aromatic aldehydes. R-CHOoverset("Tollenes reagent ")rarrR-COOH+Ag("Silver mirror") Strong oxidising agents like KMnO_(4)//H^(+),HNO_(3) K_(2)Cr_(2)O_(7)//H^(+) oxidise aldehydes as well as ketones. Open chain ketnoes on oxidation give mixture of two carboxylic acids. Oxidation of unsymmetrical ketones takes place acording to Popoff's rule. According to this rule, alpha whose bond breks in oxidation always belongs to the alkyl group which has more number of carbons. Tollens' reagent gives positive test with :

Tollens reagent || Fehling's solution || Benedict's solution || Schiff test || PopOFf's rule || Oxidation OF ketone

Rules

Rules

State the Kirchhoff's rules used in electric networks. How are these rules justified ?

Chemical Properties OF Carbonyl Compound || Oxidation OF Aldehyde and Ketone * By KMnO4/H(+) or OH(-) or K2Cr2O7/H(+) || Oxidation by H2CrO4 ||Oxidation OF Unsymmetrical Ketones(PopOFf's Rule) - POC OF Carbonyl Compounds (1) Addition OF NaHSO3 (2) 2,4- DN