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IUPAC name of [Pt(NH(3))(2)Cl(NO(2))] is...

IUPAC name of `[Pt(NH_(3))_(2)Cl(NO_(2))]` is

A

Platinum diaminechloronitrite

B

Chloronitrito-N-ammineplatinum (II)

C

Diamminechloridonitrito-N-platinum (II)

D

Diamminechloronitrito-N-platinate (II)

Text Solution

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The correct Answer is:
To determine the IUPAC name of the coordination compound \([Pt(NH_3)_2Cl(NO_2)]\), we can follow these steps: ### Step 1: Identify the ligands The ligands in the complex are: - \(NH_3\) (ammine) - \(Cl^-\) (chlorido) - \(NO_2^-\) (nitrito) ### Step 2: Determine the oxidation state of the central metal Let the oxidation state of platinum (Pt) be \(x\). - The oxidation state of \(NH_3\) is 0 (since it is a neutral ligand). - The oxidation state of \(Cl\) is -1. - The oxidation state of \(NO_2\) is -1. The overall charge of the complex is 0. Therefore, we can set up the equation: \[ x + 2(0) + (-1) + (-1) = 0 \] This simplifies to: \[ x - 2 = 0 \] Thus, \(x = +2\). The oxidation state of platinum is +2. ### Step 3: Name the ligands in alphabetical order When naming the ligands, we list them in alphabetical order regardless of their charge: 1. Chlorido (from Cl) 2. Nitrito (from NO2) 3. Ammine (from NH3) ### Step 4: Use the appropriate prefixes for the ligands - There are 2 ammine ligands, so we use the prefix "di". - There is 1 chlorido ligand, so we use "mono" (though "mono" is often omitted). - There is 1 nitrito ligand, so we use "mono" (also often omitted). ### Step 5: Combine the names and include the oxidation state of the metal Putting it all together, we have: - Ligands: diammine, chlorido, nitrito - Central metal: platinum - Oxidation state: II (indicated as "platinum(II)") ### Final IUPAC Name The IUPAC name of the compound \([Pt(NH_3)_2Cl(NO_2)]\) is: **diammine chlorido nitrito platinum(II)** ---

To determine the IUPAC name of the coordination compound \([Pt(NH_3)_2Cl(NO_2)]\), we can follow these steps: ### Step 1: Identify the ligands The ligands in the complex are: - \(NH_3\) (ammine) - \(Cl^-\) (chlorido) - \(NO_2^-\) (nitrito) ...
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