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Identify the correct statements for the ...

Identify the correct statements for the behaviour of ethane-1, 2-diamine as a ligand.

A

It is a neutral ligand

B

It is a didentate ligand

C

It is a chelating ligand

D

It is a unidentate ligand

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the behavior of ethane-1,2-diamine as a ligand, we will analyze each statement provided in the options. ### Step-by-Step Solution: 1. **Understanding the Structure of Ethane-1,2-diamine**: - Ethane-1,2-diamine has the chemical formula NH2CH2CH2NH2. - It contains two amine (-NH2) groups attached to a two-carbon chain. **Hint**: Draw the structure of ethane-1,2-diamine to visualize the donor sites. 2. **Identifying the Type of Ligand**: - A ligand can be classified based on the number of donor atoms it has. - Ethane-1,2-diamine has two nitrogen atoms that can donate lone pairs to a metal ion. **Hint**: Remember that a bidentate ligand has two donor sites. 3. **Analyzing Each Statement**: - **Statement 1**: "It is a neutral ligand." - Ethane-1,2-diamine does not carry any overall charge, making it a neutral ligand. - **Conclusion**: This statement is **correct**. - **Statement 2**: "It is a bidentate ligand." - Since it has two nitrogen atoms that can each donate a lone pair, it qualifies as a bidentate ligand. - **Conclusion**: This statement is **correct**. - **Statement 3**: "It is a chelating ligand." - A chelating ligand forms a ring structure with a metal ion. Ethane-1,2-diamine can form a five-membered ring with a metal ion by coordinating through both nitrogen atoms. - **Conclusion**: This statement is **correct**. - **Statement 4**: "It is a unidentate ligand." - A unidentate ligand has only one donor site. Since ethane-1,2-diamine has two donor sites, it cannot be classified as unidentate. - **Conclusion**: This statement is **incorrect**. 4. **Final Answer**: - The correct statements about ethane-1,2-diamine as a ligand are: - 1. It is a neutral ligand. - 2. It is a bidentate ligand. - 3. It is a chelating ligand. ### Summary of Correct Statements: - The correct statements are 1, 2, and 3.

To solve the question regarding the behavior of ethane-1,2-diamine as a ligand, we will analyze each statement provided in the options. ### Step-by-Step Solution: 1. **Understanding the Structure of Ethane-1,2-diamine**: - Ethane-1,2-diamine has the chemical formula NH2CH2CH2NH2. - It contains two amine (-NH2) groups attached to a two-carbon chain. ...
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