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Why is the reactivity of all the three c...

Why is the reactivity of all the three classes of alcohols with conc. HCl and `ZnCl_(2)` (Lucas reagent) different ?

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To understand why the reactivity of the three classes of alcohols (primary, secondary, and tertiary) with concentrated HCl and ZnCl₂ (Lucas reagent) is different, we need to analyze the stability of the carbocations formed during the reaction. Here’s a step-by-step breakdown of the reasoning: ### Step 1: Understanding the Reaction with Lucas Reagent When an alcohol reacts with Lucas reagent (HCl and ZnCl₂), the alcohol undergoes a substitution reaction where the hydroxyl (-OH) group is replaced by a chloride (-Cl) ion. The first step involves the formation of a carbocation after the -OH group leaves. ### Step 2: Carbocation Formation The stability of the carbocation formed during the reaction is crucial. The three classes of alcohols yield different carbocations: - **Primary Alcohols** (1°): Form a primary carbocation (R-CH₂⁺), which is less stable. ...
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Zn(s)+2HCl to ZnCl_(2)+H_(2)

Zn(s)+2HCl to ZnCl_(2)+H_(2)

NCERT EXEMPLAR ENGLISH-ALCOHOLS, PHENOLS AND ETHERS-All Questions
  1. Preparation of alcohols from alkenes involves the electrophilic attack...

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  2. Explain why is O=C=O non polar while R-O-R is polar ?

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  3. Why is the reactivity of all the three classes of alcohols with conc. ...

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  4. Write steps to carry out the conversion of phenol to aspirin.

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  5. Nitration is an example of aromatic electrophilic substitution and its...

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  6. In Kolbe's reactio insteaded of phenol, phenoxide ion is treated with ...

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  7. Dipole moment of phenol is smaller than that of methanol. Why ?

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  8. Ethers can be prepared by Williamson synthesis which an alkyl halide i...

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  9. Why is the C-O-H bond angle in alcohols slightly less than the tetrahe...

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  10. Explain why low molecular mass alcohols are soluble in water ?

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  11. Explain why p-nitrophenol is more acidic than phenol ?

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  12. Explain why alcohols and ethers of comparable molecular mass have diff...

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  13. The carbon-oxygen bond in phenol is slightly stronger than that in met...

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  14. Arrange water, ethanol and phenol in increasing order of acidity and g...

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  15. Match the structures of the compounds given in Column I with the name ...

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  16. Match the starting material given in Column I with the products formed...

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  17. Match the items of Column I with items of Column II.

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  18. Match the items of Column I with items of Column II.

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  19. Assertion (A) Addition reaction of water to but-1-ene in acidic medium...

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  20. Assertion (A) p-nitrophenol is more acidic than phenol. Reason (R) N...

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