Home
Class 12
CHEMISTRY
Nitration is an example of aromatic elec...

Nitration is an example of aromatic electrophilic substitution and its rate depends upon the group already present in the benzene ring. Out of benzene and phenol, which one is more easily nitrated and why ?

Text Solution

AI Generated Solution

**Step-by-Step Solution:** 1. **Understanding Nitration**: Nitration is a type of aromatic electrophilic substitution reaction where a nitro group (NO2) is introduced into an aromatic ring. The reaction typically involves a nitrating mixture of concentrated nitric acid (HNO3) and concentrated sulfuric acid (H2SO4). 2. **Formation of Electrophile**: In the nitration process, concentrated H2SO4 protonates HNO3, leading to the formation of a nitronium ion (NO2+), which acts as the electrophile. The reaction can be summarized as follows: - HNO3 + H2SO4 → NO2+ + HSO4- + H2O 3. **Comparison of Benzene and Phenol**: The question asks to compare the nitration of benzene and phenol. ...
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDE, KETONES AND CARBOXYLIC ACIDS

    NCERT EXEMPLAR ENGLISH|Exercise Long Answer Type Questions|4 Videos

Similar Questions

Explore conceptually related problems

Out of phenol and benzene, which can be more easily nitrated ?

Electrophilic substitution in case of aromatic amines takes place more readily than in benzene.

Why toluene can be more easily nitrated than benzene ?

Out of benzene, m–dinitrobenzene and toluene which will undergo nitration most easily and why?

Which of the following reactions is not an example of electrophilic substitution in benzene ring?

The most deactivating group for electrophilic substitution reaction in benzene ring is

Of the following four groups are m- directing when present on a benzene ring. The one which is not meta-directing is:

Out of -OH and -NO_2 groups, which deactivates the benzene ring and why?

The general electrophilic substitution reaction (replacement of H. by an electrophilic which is an electron deficient species) in aromatic ring is represented as followed. An electrophilic attacks on ortho and para positions which respect to a stronger +m group are present in benzene ring and the electrophilie attacks at meta position with respect to stronger -m group if two -m groups are present in benzene ring. What will be the product when electrophile Br^(o+) attacks on

NCERT EXEMPLAR ENGLISH-ALCOHOLS, PHENOLS AND ETHERS-All Questions
  1. Why is the reactivity of all the three classes of alcohols with conc. ...

    Text Solution

    |

  2. Write steps to carry out the conversion of phenol to aspirin.

    Text Solution

    |

  3. Nitration is an example of aromatic electrophilic substitution and its...

    Text Solution

    |

  4. In Kolbe's reactio insteaded of phenol, phenoxide ion is treated with ...

    Text Solution

    |

  5. Dipole moment of phenol is smaller than that of methanol. Why ?

    Text Solution

    |

  6. Ethers can be prepared by Williamson synthesis which an alkyl halide i...

    Text Solution

    |

  7. Why is the C-O-H bond angle in alcohols slightly less than the tetrahe...

    Text Solution

    |

  8. Explain why low molecular mass alcohols are soluble in water ?

    Text Solution

    |

  9. Explain why p-nitrophenol is more acidic than phenol ?

    Text Solution

    |

  10. Explain why alcohols and ethers of comparable molecular mass have diff...

    Text Solution

    |

  11. The carbon-oxygen bond in phenol is slightly stronger than that in met...

    Text Solution

    |

  12. Arrange water, ethanol and phenol in increasing order of acidity and g...

    Text Solution

    |

  13. Match the structures of the compounds given in Column I with the name ...

    Text Solution

    |

  14. Match the starting material given in Column I with the products formed...

    Text Solution

    |

  15. Match the items of Column I with items of Column II.

    Text Solution

    |

  16. Match the items of Column I with items of Column II.

    Text Solution

    |

  17. Assertion (A) Addition reaction of water to but-1-ene in acidic medium...

    Text Solution

    |

  18. Assertion (A) p-nitrophenol is more acidic than phenol. Reason (R) N...

    Text Solution

    |

  19. Assertion (A) IUPAC name of the compound CH(3)-underset(CH(3))unders...

    Text Solution

    |

  20. Assertion (A) Bond angle is ethers is slightly less than tetrahedral a...

    Text Solution

    |