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Explain why p-nitrophenol is more acidic...

Explain why p-nitrophenol is more acidic than phenol ?

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To explain why p-nitrophenol is more acidic than phenol, we can break down the reasoning into several steps: ### Step 1: Understanding the Structures - **Phenol** has the structure C6H5OH, where the hydroxyl (-OH) group is directly attached to a benzene ring. - **p-Nitrophenol** has the structure C6H4(NO2)OH, where a nitro group (-NO2) is attached to the benzene ring at the para position relative to the hydroxyl group. ### Step 2: Identifying the Effects of the Nitro Group - The nitro group is a strong electron-withdrawing group due to its -I (inductive) and -R (resonance) effects. ...
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Assertion (A) p-nitrophenol is more acidic than phenol. Reason (R) Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.

Explain why is ortho-nitrophenol more acidic than ortho-methoxyphenol ?

Explain the following observations: o-and p-nitrophenols are more acidic than phenol.

Ortho and para nitrophenols are more acidic than phenol. Draw the resonance structures of the corresponding phenoxide ions.

Phenol is more acidic than alcohol because :

Assertion : Ortho nitro phenol is more acidic than meta nitro phenol Reason : Ortho nitro phenol has more –I effect than meta nitro phenol

NCERT EXEMPLAR ENGLISH-ALCOHOLS, PHENOLS AND ETHERS-All Questions
  1. Why is the C-O-H bond angle in alcohols slightly less than the tetrahe...

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  2. Explain why low molecular mass alcohols are soluble in water ?

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  3. Explain why p-nitrophenol is more acidic than phenol ?

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  4. Explain why alcohols and ethers of comparable molecular mass have diff...

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  5. The carbon-oxygen bond in phenol is slightly stronger than that in met...

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  6. Arrange water, ethanol and phenol in increasing order of acidity and g...

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  7. Match the structures of the compounds given in Column I with the name ...

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  8. Match the starting material given in Column I with the products formed...

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  9. Match the items of Column I with items of Column II.

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  10. Match the items of Column I with items of Column II.

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  11. Assertion (A) Addition reaction of water to but-1-ene in acidic medium...

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  12. Assertion (A) p-nitrophenol is more acidic than phenol. Reason (R) N...

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  13. Assertion (A) IUPAC name of the compound CH(3)-underset(CH(3))unders...

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  14. Assertion (A) Bond angle is ethers is slightly less than tetrahedral a...

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  15. Assertion (A) Boiling points of alcohols and ethers are high. Reason...

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  16. Assertion (A) Like bromination of benzene, bromination of phenol is al...

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  17. Assertion (A) o-nitrophenol is less soluble in water than the m and p-...

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  18. Assertion (A) Ethanol is a weaker acid than phenol. Reason (R) Sodiu...

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  19. Assertion (A) Phenol forms 2, 4, 6-tribromophenol o treatment with Br(...

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  20. Assertion (A) Phenols give o-and p-nitrophenol on nitration with conc....

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